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A: I have given the answer in the explanation section. Hope you will understand that.
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- In which compound is the halogen substituted most rapidly by aq hydroxide ions? a. CH3CH2CH2CH2Cl b. (CH3)3CI c. (CH3)3CCl d. CH3CH2CH2CH2IProvide the product most likely to form from reaction of each reagent with 1-methylcyclohexene. You may ingore stereochemistry for this question. Br2 H-Br H-Br, PhC(O)OOC(O)Ph N-bromosuccinimide, PhC(O)OOC(O)Ph A. B. C. D.Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reactionoccurs.a. H2 + Pd-Cb. H2 + Lindlar catalystc. Na, NH3d. CH3CO3He. [1] CH3CO3H; [2] H2O, HO–f. [1] OsO4 + NMO; [2] NaHSO3, H2Og. KMnO4, H2O, HO–h. [1] LiAlH4; [2] H2Oi. [1] O3; [2] CH3SCH3j. (CH3)3COOH, Ti[OCH(CH3)2]4, (–)-DETk. mCPBAl. Product in (k); then [1] LiAlH4; [2] H2O
- These reagents can produce ketones with alkynes A. BH3, THF, H2O2 B. KMnO4 C. O3 D. H2SO4, H2O, HgSO4 choices:A,DB,CA,B,CA,B,C,D1.Label kinetic product 2.Label the thermodynamic product 3.Predict the four products from reaction of alkene with one equivalent HBrreactions and products for C9H8O4 C9H8O4 + O2 --> C9H8O4 + H2O --> C9H8O4 + HCl --> C9H8O4 + OH- --> C9H8O4 + Na --> C9H8O4 + F -->
- As reaction of (CH3)2CO with LIC≡CH followed by H2O affords compound D, which has a molecular ion in its mass spectrum at 84 and prominent absorptions in its IR spectrum at 3600−3200, 3303, 2938, and 2120 cm−1. D shows the following 1H NMR spectral data: 1.53 (singlet, 6 H), 2.37 (singlet, 1 H), and 2.43 (singlet, 1 H) ppm. What is the structure of D?What steps are needed to prepare phenylacetylene, C6H5C = CH, from each compound: (a) C6H5CH2CHBr2; (b) C6H5CHBrCH3; (c) C6H5CH2CH2OH?Predict the major products of the following reactions, including stereochemistry where appropriate. cyclooctanol + NaOCl>HOAc (d) cyclopentylmethanol + CrO3 # pyridine # HCl
- Draw all products of the reaction of (1S,2R)-1-bromo-1,2-dimethylcyclohexane in 80%H2O/20%CH3CH2OHat room temperature..The stereochemistry of the products of reduction depends on the reagent used, as you learned in Sections 20.5 and 20.6. With this in mind, how would you convert 3,3-dimethylbutan-2-one [CH3COC(CH3)3] to: (a) racemic 3,3-dimethylbutan-2- ol [CH3CH(OH)C(CH3)3]; (b) only (R)-3,3-dimethylbutan-2-ol; (c) only (S)-3,3-dimethylbutan-2-ol?As we will learn in Chapter 20, reaction of (CH3)2CO with LiC ≡ CH followed by H2O affords compound D, which has a molecular ion in its mass spectrum at 84 and prominent absorptions in its IR spectrum at 3600–3200, 3303, 2938, and 2120 cm. D shows the following 1H NMR spectral data: 1.53 (singlet, 6 H), 2.37 (singlet, 1 H), and 2.43 (singlet, 1 H) ppm. What is the structure of D?