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- 2 Two nitroimidazole drugs, misonidazole and tinidazole have single-electron reduction potentials of -0.389 V and -0.464 V respectively: Misonidazole + e- ➝ Misonidazole·- E0 = -0.389 V Tinidazole + e- ➝ Tinidazole·- E0 = -0.464 V The reduction potential of the NADH/NAD couple is -0.324 V, and the reduction potential of the ferrodoxin couple is -0.460 V: NAD+ + e- ➝ NADH E0 = -0.324 V [Ferrodoxin]3+ + e- ➝ [Ferrodoxin]2+ E0 = -0.460 V Explain which, if any, of misonidazole and tinidazole will be selectively reduced in protozoa over mammalian cells. In your answer you should calculate any reduction potentials you need.What is the oxidizing agent (oxidant) when acidified potassium permanganate reacts with hydrogen peroxide KMnO4 + H2O2Is C18H32O2+2H2 =C18H36O2 an oxidation or reduction reaction?
- The oxidation of peroxodisulfate ion: S2O82–(aq) + 2I–(aq) à 2SO42–(aq) + I2(aq) Which of the following properties should be monitored in order to BEST follow the progress of this oxidation reaction? Select one: a. Colour intensity of the reaction mixture b. Volume of the reaction mixture c. Mass of the reaction mixture d. Pressure of the reaction mixtureExplain about degradation of azo dyes in wastewater using micro-nano bubble treatment.Calculate the standard free energy change (AG") for the transfer of electrons from succinate to ubiquinone: Succinate + ubiquinone O -2.7 kJ/mol relevant half-reactions and standard reduction potentials: fumarate + 2H* + 2 e™ H succinate ubiquinone + 2 H+ + 2 e² = O2.7 kJ/mol -8.7 kJ/mol O 14.7 kJ/mol succinate dehydrogenase O -6.0 kJ/mol Fumarate + ubiquinol ubiquinol E = 0.031 V ED - 0.045 V Atte 1 H
- Pb 2+ +2e−→PbE ∘ =1.69 V If PbF 2 is dissolved in water, a Pb∣Pb 2+ ∥SCE reads 1.37 V. What is the Ksp of PbF 2 ?Given the standard reduction potentials (Eo’) for ubiquinone (Q) and NADP+provided below, consider the following questions.Q + 2H+ + 2e- ---> QH2 Eo’ = 0.04 VNADP+ + H+ + 2e- ---> NADPH Eo’ = -0.32 V - Calculate the standard ΔEo’ for the oxidation of NADPH by Q. From the reactantsin your derived redox reaction, indicate the oxidant and reductant.- Calculate the standard free energy of the redox reaction in part (a) and indicate if thereaction is exergonic or endergonic.If the concentration of Sn2+ ions in a solution of Sn(OH)2 was measured to be (1.41x10^-3), what is the Ksp value for Sn(OH)2?
- Chemistry Two nitroimidazole drugs, misonidazole and tinidazole have single-electron reduction potentials of -0.389 V and -0.464 V respectively: Misonidazole + e- ➝ Misonidazole·- E0 = -0.389 V Tinidazole + e- ➝ Tinidazole·- E0 = -0.464 V The reduction potential of the NADH/NAD couple is -0.324 V, and the reduction potential of the ferrodoxin couple is -0.460 V: NAD+ + e- ➝ NADH E0 = -0.324 V [Ferrodoxin]3+ + e- ➝ [Ferrodoxin]2+ E0 = -0.460 V Explain which, if any, of misonidazole and tinidazole will be selectively reduced in protozoa over mammalian cells. In your answer you should calculate any reduction potentials you need.The following cell was used for the determination of pCrO4: SCE||CrO42- (xM), Ag2CrO4 (sat’d)|Ag Calculate pCrO4 if the cell potential is 0.386.The standard state free energy of hydrolysis of phosphocreatine is ΔG° = -42.8 kJ/mol. phosphocreatine + H2O → creatine + Pi T = 20 °C Calculate the free energy change for the phosphocreatine hydrolysis in a solution of 3.50 mM creatine, 3.50 mM phosphate and 1.00 nM phosphocreatine.