The ability of a solution to resist changes to the pH from added acid or base depends upon the amount of weak acid and weak base.  The buffering capacity is the ratio of weak acid to weak base and the best buffering occurs when these are equal, making the buffering capacity equal to 1.  In the above buffer the buffering capacity is the ratio of  [H2PO4-1] to [HPO4-2], or                      Ka [H2PO4-1]          Ka (4.44 x 10-5)          Ka   (8)  [H3O+1] =  ––––––––––––– = –––––––––––––––– = –––––––––                        [HPO4-2]               (5.55 x 10-5)                   (10) Here the buffering capacity is close to 1 (0.8) and so the buffering capacity is  Blank 1. Fill in the blank, read surrounding text. When the buffering capacity is 1, the  [H3O+1] = Ka and the pH = pKa This helps chemists choose the right buffer for the needed pH.  To buffer at pH = 7, the weak acid should a pKa of close to 7, True or False ?    Blank 2. Fill in the blank, read surrounding text. the weak acid should have Ka of close to 1 x 10-7, True or False ?    Blank 3. Fill in the blank, read surrounding text.

Chemistry: An Atoms First Approach
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ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 4RQ: A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If...
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The ability of a solution to resist changes to the pH from added acid or base depends upon the amount of weak acid and weak base.  The buffering capacity is the ratio of weak acid to weak base and the best buffering occurs when these are equal, making the buffering capacity equal to 1.  In the above buffer the buffering capacity is the ratio of 

[H2PO4-1] to [HPO4-2], or

                     Ka [H2PO4-1]          Ka (4.44 x 10-5)          Ka   (8)

 [H3O+1] =  ––––––––––––– = –––––––––––––––– = –––––––––

                       [HPO4-2]               (5.55 x 10-5)                   (10)

Here the buffering capacity is close to 1 (0.8) and so the buffering capacity is  Blank 1. Fill in the blank, read surrounding text.

When the buffering capacity is 1, the  [H3O+1] = Ka

and the pH = pKa

This helps chemists choose the right buffer for the needed pH.  To buffer at pH = 7,

the weak acid should a pKa of close to 7, True or False ?    Blank 2. Fill in the blank, read surrounding text.

the weak acid should have Ka of close to 1 x 10-7, True or False ?    Blank 3. Fill in the blank, read surrounding text.

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