The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10^–8. (a)  The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution.  (b)  Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation.  (c)  Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section: Chapter Questions
Problem 106GQ: The hydrogen phthalate ion, C8HsO4, is a weak acid with Ka = 3.91 106....
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The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10^–8.

  1. (a)  The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution. 

  2. (b)  Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. 

  3. (c)  Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it. 

Expert Solution
Step 1

The word pH stands for the potency of hydrogen and it is used to measure the concentration of hydrogen ion in a solution of acid or base.

The range of pH is from 0 to 14.

The solution is acidic when pH < 7.

The solution is basic when pH > 7.

The solution is neutral when pH = 7.

The formula used in this question are:

pH = - log [H+]pH + pOH = 14

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