The decomposition of nitramide, O,NNH,, in water has the chemical equation and rate law O₂NNH₂(aq) N₂O(g) + H₂O(1) [O₂NNH₂] [H*] A proposed mechanism for this reaction is - 1. O,NNH, (aq) w O₂NNH (aq) + H* (aq) (fast equilibrium) k₁₁ 2.0₂NNH- (aq) N₂O(g) + OH- (aq) (slow) k= 3. H* (aq) + OH(aq) + H₂O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? Incorrect rate k k. ks Answer Bank k₁ k₂

Chemistry & Chemical Reactivity
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
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Problem 39PS: When healed lo a high temperature, cyclobutane, C4H8 decomposes to ethylene: C4H8(g) 2 C2H4(g) The...
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The decomposition of nitramide, O₂NNH₂, in water has the chemical equation and rate law
[O₂NNH₂]
[H*]
O₂NNH₂(aq) N₂O(g) + H₂O(1)
A proposed mechanism for this reaction is
1
k₁
1.0₂NNH₂(aq) O,NNH (aq) + H* (aq) (fast equilibrium)
k=
Incorrect
k
2. O₂NNH™ (aq) N₂O(g) + OH (aq) (slow)
-
3. H* (aq) + OH(aq) H₂O(1) (fast)
What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism?
rate k
k.
ky
Answer Bank
k₂
Transcribed Image Text:The decomposition of nitramide, O₂NNH₂, in water has the chemical equation and rate law [O₂NNH₂] [H*] O₂NNH₂(aq) N₂O(g) + H₂O(1) A proposed mechanism for this reaction is 1 k₁ 1.0₂NNH₂(aq) O,NNH (aq) + H* (aq) (fast equilibrium) k= Incorrect k 2. O₂NNH™ (aq) N₂O(g) + OH (aq) (slow) - 3. H* (aq) + OH(aq) H₂O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? rate k k. ky Answer Bank k₂
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