The decomposition reaction of atmospheric peroxyacetylnitrate (PAN) to products was studied, and the following rates were obtained. Temperature, °C Rate constant, s1 0.00 5.60 x 10-6 10.0 3.20 x 10-5 20.0 1.60 x 10 4 30.0 7.60 x 10-4 43. Fit this data into the Arrhenius equation. Give the values of the following: Slope = ( Select ) y-intercept Pearson coefficient (R) = [ Select ] activation energy of this reaction in kJ/mol [ Select ]
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![The decomposition reaction of atmospheric peroxyacetylnitrate (PAN) to products
was studied, and the following rates were obtained.
Temperature, °C Rate constant, s1
0.00
5.60 x 10-6
10.0
3.20 x 10-5
20.0
1.60 x 10 4
30.0
7.60 x 10-4
43. Fit this data into the Arrhenius equation. Give the values of the following:
Slope = ( Select )
y-intercept = I Select]
Pearson coefficient (R) = [ Select ]
activation energy of this reaction in kJ/mol = [Select ]
collision frequency factor A = I Select]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4f9ce00f-82f1-4942-99e6-129221e702b9%2F8c4cbf48-095f-4e62-82c7-742368b28424%2Fuyzfnf9_processed.jpeg&w=3840&q=75)
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- If you measured the rate of reaction at 20°C to be 1.11 x 10-5 M/s when using 0.080 M I1- and 0.040 M S2O82-. Approximately how long will the reaction take if you were to increase the temperature to 30 °C?For ferrocene (C10H10Fe) the enthalpy of sublimation is 73.2 kJ/mol and the entropy of sublimation is 243 J/mol.K. What is the sublimation temperature of ferrocene in degrees Celsius?The Ksp values of silver chromate Ag2CrO4 and silver iodate Ag(IO3) are given below. Ag2CrO4 Ag(IO3) Ksp 1.12 x 10-12 3.17 x 10-8 Based on these Ksp values, which of the following is true? Choose one option only. Options: a. In the solution consisting of 1.00 x10-4 M Ag+ and 5.00 x10-5 M CrO42-, Ag2CrO4 precipitate will form. b. In the solution consisting of 1.0 x10-4 M Ag+ and 1.0 x10-4 M IO3-, Ag(IO3) precipitate will form. c. In pure water, the solubility of Ag2CrO4 is lower than the solubility of Ag(IO3). d. In the solution consisting of 0.200 M CrO42- and 0.200 M IO3-, Ag2(CrO4) will precipitate first if we add Ag+ ions gradually into the above mixture.
- An analysis of city drinking water for total hardness was done by two students in the laboratory and produced the following results (in ppm CaCO3): Student A: 228.3, 226.4, 226.9, 227.1, and 228.6. Student B: 229.5, 226.1, 230.7, 223.8, and 227.5 1. Calculate the following for each data set: (proper significant figures, neglect units) a) Mean for student A b) Mean for student B c) Relative standard deviation for student A d) Relative standard deviation for student B e) Confidence Level for Student A at 95% (write as a range for example: 200-300) f) Confidence Level for Student B at 95% (write as a range for example: 200-300) g) Which of the student have a more precise result? (write STUDENT A or STUDENT B)The main constituents in vinegar are water and ethanoic acid (CH3COOH). In order to determine the concentration of acid in homemade vinegar, a student titrated 25 cm3 of 001 M NaOH against the vinegar. The equation for the reaction is: CH3COOH(aq) + NaOH(aq) ® CH3COONa(aq) + H2O(l) The following titration results were obtained: Burette readings (cm3) Rough 1 2 Final burette reading 20.10 38.90 31.40 Initial burette reading 0.10 20.00 12.50 Volume of vinegar used 20.00 18.90 18.90 (a) What volume of vinegar should be used in the calculation? (b) What is the mole ratio of NaOH:CH3COOH? (c) Calculate the number of moles of alkali in 25 cm3 of NaOH solution used. (d) How many moles of acid were used in the titration? (e) Calculate the…For the following reaction 3 experiments have been run and the data collected is in the following table @ 35 degrees Celsius 2 NO2F(g) ---> 2 NO2(g) + F2(g) Experiment [NO2F], M Rates, M/s 1 0.263 0.168 2 0.349 0.223 3 0.421 0.269 a) How long will it take for a 65% NO2F solution to become a 31% NO2F solution @35 degrees Celsius?(Hint: Use mass ratios and assume ~1g/ml for density of solutions to get you started) b) It has been determined that at 75 degrees Celsius the rate constant is 1.046 s-1. Calculate the activation energy for the decomposition of NO2F. [Hint: ]ln?1?2=?a?(1?2―1?1) c) What is the half-life of a 35% solution of NO2F @ 35 degrees Celsius?
- Why is it necessary to specify the temperaturewhen making a table listing ∆G values?Combustion of a fuel sample in a bomb calorimeter increases the temperature of the entire system by 5.10 °C if the calorimeter contains 1700 g of water, but only by 4.00 °C if the calorimeter contains 2200 g of water. What is the heat capacity of the dry bomb calorimeter assembly? Assume that the specific heat capacity of water is 4.18 J g–1 °C–1.Two solutions, 250.0 mL of 1.00 M CaCl2(aq) and 250.0 mL of 1.00 M K2SO4(aq), are combined, and the temperature decreased by 2.40 degrees C. Determine qrxn per mole of CaSO4(s) formed in the reaction. A) +12.0 kJ/mol B) -12.0 kJ/mol C) +6.00 kJ/mol D) -6.00 kJ/mol
- The following reaction plays a key role in the destruction of ozone in the atmosphere: Cl(g)+ O3 (g)-> ClO(g)+O2 (g) Given the standard molar entropies (S°) below, calculate the ΔS for this reaction. S°C1O = 218.9 J/mol*K S°O3 = 238.8 J/mol*K S°Cl = 165.2 J/mol*K S°O2= 205.0 J/mol*K _______ J/K = ΔSIn kool aid chromatography, what factors affect the efficiency of the column? Also discuss the Van-Deemter equation.The standard heat of combustion of liquid methyl cyclopentane, C6H12(l),C6H12(l), was measured to be −3937.7 kJ/mol.−3937.7 kJ/mol. What is Δ?̂ ∘f C6H12(l),ΔH^f C6H12(l)∘, the standard heat of formation of liquid methyl cyclopentane?