The equivalence-point pH is NOT 7.00 here. Why not??

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter15: Complex Acid/base Systems
Section: Chapter Questions
Problem 15.29QAP
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Titration Curves: Weak acid with strong base
14.0
The equivalence-point
pH is NOT 7.00 here.
Why not??
Excess base
results in high pH
12.0
Equivalence
point
10.0
Cole „nange
piienolphthalein
Bromphenol blue was ok
for the strong acid/strong
base titration, but it
changes color far too early
8.0
6.0
pH = pka
to be useful here.
4.0
Color change
| bromphenol blue
Excess acid
results in low pH
2.0
0.0
0.0
5.0
10.0
15.0
20.0
25.0
30.0
Volume of 0.500 M NaOH, mL
CH;COOH + NaOH → Na CH,CO0 + H,0
Hd
Transcribed Image Text:Titration Curves: Weak acid with strong base 14.0 The equivalence-point pH is NOT 7.00 here. Why not?? Excess base results in high pH 12.0 Equivalence point 10.0 Cole „nange piienolphthalein Bromphenol blue was ok for the strong acid/strong base titration, but it changes color far too early 8.0 6.0 pH = pka to be useful here. 4.0 Color change | bromphenol blue Excess acid results in low pH 2.0 0.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 Volume of 0.500 M NaOH, mL CH;COOH + NaOH → Na CH,CO0 + H,0 Hd
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