The following complexation reaction was carried out by using 2.5 g of cobalt(II)nitrate hexahydrate with 10.0 g of ammonium carbonate and excess of ammonia and hydrogen peroxide. Co(NO3)2.6H2O + 4NH3(aq) + (NH4)2CO3 + ½ H2O2 → [Co(NH3)4CO3]NO3 +  NH4NO3 + 6H2O + NH4OH     Which is the limiting reagent in the above reaction? Mention how you will identify it.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter3: Equation, The Mole, And Chemical Formulas
Section: Chapter Questions
Problem 3.157QE
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The following complexation reaction was carried out by using 2.5 g of cobalt(II)nitrate hexahydrate with 10.0 g of ammonium carbonate and excess of ammonia and hydrogen peroxide.

Co(NO3)2.6H2O + 4NH3(aq) + (NH4)2CO3 + ½ H2O2 → [Co(NH3)4CO3]NO3 +  NH4NO3 + 6H2O + NH4OH  

 

  1. Which is the limiting reagent in the above reaction? Mention how you will identify it.

 

2. Write the oxidation and reduction half equations of this reaction.

                                                                                                           

  3.  How did Werner first explain bonding in complexes? (Refer website)

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