The following initial rate data are for the reaction of UO2™ with hydrogen ion in aqueous solution: 2 UO,+ + 4 H* --→ U4+ + UO2²+ + 2 H20

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Chapter12: Chemical Kinetics
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Problem 32E: The following data were obtained for the gas-phase decomposition of dinitrogen pentoxide,...
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The following initial rate data are for the reaction of UO2T with hydrogen ion in aqueous solution:
2 UO2* +4
+ --> U4+ + U0,2+ + 2 H20
Experiment
[U02*lo, M
[H*]o, M
Initial Rate, M s-
3.93x10-3
7.86x10-3
3.93x10-3
1
0.550
1.24x10-3
2
0.550
4.96x10-3
3
1.10
2.48x10-3
7.86x10-3
1.10
9.92x10-3
4
Based on these experimental data, what is the correct rate law for this reaction?
O rate = k [UO2*j² [H*j²
rate = k [UO2*j2
%3D
rate = k [UO2*j2 [H*]
%3D
rate =
k [UO2*] [H*j?
rate = k [H*j?
%D
Transcribed Image Text:+ The following initial rate data are for the reaction of UO2T with hydrogen ion in aqueous solution: 2 UO2* +4 + --> U4+ + U0,2+ + 2 H20 Experiment [U02*lo, M [H*]o, M Initial Rate, M s- 3.93x10-3 7.86x10-3 3.93x10-3 1 0.550 1.24x10-3 2 0.550 4.96x10-3 3 1.10 2.48x10-3 7.86x10-3 1.10 9.92x10-3 4 Based on these experimental data, what is the correct rate law for this reaction? O rate = k [UO2*j² [H*j² rate = k [UO2*j2 %3D rate = k [UO2*j2 [H*] %3D rate = k [UO2*] [H*j? rate = k [H*j? %D
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