The following Ka values have been experimentally determined for formic and acetic acids. Acid Ka Formic acid, HCO2H 1.8x10-4 Acetic acid, CH3CO2H 1.8x10-5   Which of the following solutions will have the highest pH? 1.0 M sodium acetate, NaCH3CO2 1.0 M sodium formate, NaHCO2 1.0 M formic acid, HCO2H 1.0 M acetic acid, CH3CO2H Cannot be determined from the information given. What is the pH of a buffer solution

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter15: Solutions Of Acids And Bases
Section: Chapter Questions
Problem 15.135QE
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The following Ka values have been experimentally determined for formic and acetic acids.
Acid Ka
Formic acid, HCO2H 1.8x10-4
Acetic acid, CH3CO2H 1.8x10-5
 
Which of the following solutions will have the highest pH?
1.0 M sodium acetate, NaCH3CO2
1.0 M sodium formate, NaHCO2
1.0 M formic acid, HCO2H
1.0 M acetic acid, CH3CO2H
Cannot be determined from the information given.

What is the pH of a buffer solution of 0.10 M solution of acetic acid and 0.10 M sodium acetate? Support your answer.

If 0.05 mol of sodium hydroxide, NaOH, are added to the acetic acid/acetate buffer from part B, what would be the resulting pH?  (Recall: the original buffer had 0.10 M acetic acid and 0.10 M acetate.).  Show/describe your work.
 

For what pH is a formic acid/formate buffer best suited?  Explain your answer. 

Predict the magnitude (K >1, K<1, K = 1) for the equilibrium constant for the following reaction.  Provide reasoning for your prediction.

HCOOH(aq) + CH3COO-(aq) <=> HCOO-(aq) + CH3COOH(aq)

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