The gas phase decomposition of phosphine at 120 °C PH3(g) →→→1/4 P4(g) + 3/2 H₂(g) is first order in PH3. During one experiment it was found that when the initial concentration of PH3 was 0.0674 M, the concentration of PH3 dropped to 0.0104 M after 67.0 s had passed. Based on this experiment, the rate constant for the reaction is

Chemistry & Chemical Reactivity
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 21PS: At 573 K, gaseous NO2(g) decomposes, forming NO(g) and O2(g). If a vessel containing NO2(g) has an...
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The gas phase decomposition of phosphine at 120 °C
PH3(g)→→→→→→1/4 P4(g) + 3/2 H₂(g)
is first order in PH3.
During one experiment it was found that when the initial concentration of PH3 was 0.0674 M, the concentration of PH3 dropped
to 0.0104 M after 67.0 s had passed.
Based on this experiment, the rate constant for the reaction is |
S-1
Transcribed Image Text:The gas phase decomposition of phosphine at 120 °C PH3(g)→→→→→→1/4 P4(g) + 3/2 H₂(g) is first order in PH3. During one experiment it was found that when the initial concentration of PH3 was 0.0674 M, the concentration of PH3 dropped to 0.0104 M after 67.0 s had passed. Based on this experiment, the rate constant for the reaction is | S-1
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