The gas phase reaction of carbon monoxide with nitrogen dioxide is believed to occur by the following mechanism: step 1 slow: 2 NO₂ -NO3 + NO step 2 fast: NO3 + CO NO₂ + CO₂ (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. 1 (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]m [B]"..., where "1" is understood (so don't write it) for m, n, etc. Rate =

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
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Problem 11.70PAE: The label on a bottle of 3% (by volume) hydrogen peroxide, H2O2, purchased at a grocery store,...
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The gas phase reaction of carbon monoxide with nitrogen dioxide is believed to occur by the following
mechanism:
step 1
step 2
slow: 2 NO₂ -
fast: NO3 + CO
+
NO3 + NO
NO₂ + CO₂
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not
needed, leave it blank.
1-0
(2) Which species acts as a catalyst? Enter formula. If none, leave box blank:
(3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank:
(4) Complete the rate law for the overall reaction that is consistent with this mechanism.
Use the form k[A]m [B]"..., where "1" is understood (so don't write it) for m, n, etc.
Rate =
Transcribed Image Text:The gas phase reaction of carbon monoxide with nitrogen dioxide is believed to occur by the following mechanism: step 1 step 2 slow: 2 NO₂ - fast: NO3 + CO + NO3 + NO NO₂ + CO₂ (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. 1-0 (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]m [B]"..., where "1" is understood (so don't write it) for m, n, etc. Rate =
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