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- Give reasons for the following :(i) Ethyl iodide undergoes SN2 reaction faster than ethyl bromide.(ii) (±) 2-Butanol is optically inactive.(iii) C—X bond length in halobenzene is smaller than C—X bond length in CH3—X.How will you convert the following compounds to benzene?(i) Acetylene (ii) Benzoic acid(iii) Cyclohexane (iv) Benzene diazonium chloride.When 1-butanol is treated with conc. H2SO4 and heat .A product 'A' is formed from the reaction. Treatment of 'A' with HCl/H2O gives 'B'. Treatment of 'A' with cold KMnO4/OH- gives 'C' Treatment of 'A' with hot KMnO4 /OH- gives 'D' followed by acidification of the mixture to give 'E' 1. identify the compounds represented by A,B,C,D and E.
- What product is obtained from the reaction of excess benzene with each of the following reagents? a. isobutyl chloride + AlCl3 b. 1-chloro-2,2-dimethylpropane + AlCl3 c. dichloromethane + AlCl3What happens if toluene is treated with: a) Br2/UV, b) Cl2/AlCl3, c) HNO3conc./H2SO4conc., d) (CH3)2CHBr/ZnBr2, e) KMnO4/H+, t°C. Name all the products.Which of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4
- Write reactions of propan-1-ol with the following reagents: a. Na b. PCl5Give reasons for the following: (i) p-nitrophenol is more acidic than p-methylphenol. (ii) Bond length of C—O bond in phenol is shorter than that in methanol. (iii) (CH3)3C—Br on reaction with sodium methoxide (Na+ _OCH3) gives alkene as the main product and not an ether.a. Compound X is benzene, Y is acetic anhydride acid. Complete the following scheme and determine Z! b. Determine which reagents except acetic acid anhydrides can replace Y!
- 2-bromo-2-methylbutane undergoes hydrolysis reaction with water, H2O toform compound W. Compound X and compound Y are produced when 2-bromo-2-methylbutane undergoes elimination reaction with alcoholic ofsodium hydroxide, NaOH. (i) Draw the structural formula of compounds W, X and YChoose the appropriate reagent for the following reaction. A) TsCl/pyridine B) SOCl2/pyridine C) ZnCl2 D) PBr3 E) HIPredict the major products (including stereochemistry) when cis-3-methylcyclohexanol reacts with the following reagents. (a) PBr3 (b) SOCl2 (c) Lucas reagent