The product of the following reactions will be ________ . 1) Benzene + + 1/2 I2 + HNO3 2) Formyl chloride (acyl chloride of formic acid-HCO2H) and AlCl3 4-iodobenzoic acid 3-iodobenzaldehyde 2-iodobenzaldehyde benzoic acid 3-iodobenzylalcohol

The product of the following reactions will be ________ . 1) Benzene + + 1/2 I2 + HNO3 2) Formyl chloride (acyl chloride of formic acid-HCO2H) and AlCl3 4-iodobenzoic acid 3-iodobenzaldehyde 2-iodobenzaldehyde benzoic acid 3-iodobenzylalcohol

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.50P

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Concept explainers

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.

Question

100%

The product of the following reactions will be ________ .

1) Benzene + + 1/2 I₂ + HNO₃

2) Formyl chloride (acyl chloride of formic acid-HCO₂H) and AlCl₃

		4-iodobenzoic acid
		3-iodobenzaldehyde
		2-iodobenzaldehyde
		benzoic acid
		3-iodobenzylalcohol

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