The solubility of CaCO3 in water is about 7 mg L-1 . Show how one can calculate the solubility product of BaCO3 from this information and from the fact that when sodium carbonate solution is added slowly to a solution containing equimolar concentrations of Ca2+ and Ba2+, no CaCO3 is formed until about 90% of the Ba2+ has been precipitated as BaCO3.

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter15: Equilibria Of Other Reaction Classes
Section: Chapter Questions
Problem 11E: The Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities...
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The solubility of CaCO3 in water is about 7 mg L-1 . Show how one can calculate the solubility product of BaCO3 from this information and from the fact that when sodium carbonate solution is added slowly to a solution containing equimolar concentrations of Ca2+ and Ba2+, no CaCO3 is formed until about 90% of the Ba2+ has been precipitated as BaCO3.

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