The table below presents thermodynamic data for the dissociation reaction of acetic acid, CH3COOH And of acetic trichloroacetic acid CCl3COOOH. CH3COOH(l) + H2O(l) ⇄ CH3COO(aq)− + H3O(aq)+ CCl3COOH(l) + H2O(l) ⇄ CCl3COO(aq)− + H3O(aq)+ Kc (25°C) ΔS° (J/mol·K) ΔH° (kJ/mol) ΔG° (kJ/mol) 1.77×10 -5 -2.51 27.12 CH3COOH -13.66 3.93 CCl3COOOH Explain the negative sign of ΔS to the dissociation reaction of triacid
The table below presents thermodynamic data for the dissociation reaction of acetic acid, CH3COOH And of acetic trichloroacetic acid CCl3COOOH. CH3COOH(l) + H2O(l) ⇄ CH3COO(aq)− + H3O(aq)+ CCl3COOH(l) + H2O(l) ⇄ CCl3COO(aq)− + H3O(aq)+ Kc (25°C) ΔS° (J/mol·K) ΔH° (kJ/mol) ΔG° (kJ/mol) 1.77×10 -5 -2.51 27.12 CH3COOH -13.66 3.93 CCl3COOOH Explain the negative sign of ΔS to the dissociation reaction of triacid
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 83QRT: Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate,...
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The table below presents
CH3COOH(l) + H2O(l) ⇄ CH3COO(aq)− + H3O(aq)+
CCl3COOH(l) + H2O(l) ⇄ CCl3COO(aq)− + H3O(aq)+
Kc (25°C) | ΔS° (J/mol·K) | ΔH° (kJ/mol) | ΔG° (kJ/mol) | |
1.77×10 -5 | -2.51 | 27.12 | CH3COOH | |
-13.66 | 3.93 | CCl3COOOH |
Explain the negative sign of ΔS to the dissociation reaction of triacid
Acetic chlorine, CCl3COOOH.
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