The thermal decomposition of nitryl chloride is proposed to occur by the following mechanism: step 1 slow: NO2CI → NO2 + CI step 2 fast: CI + NO2CI –→ NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]™[B]"... , where '1' is understood (so don't write it) for m, n etc.) Rate =

The thermal decomposition of nitryl chloride is proposed to occur by the following mechanism: step 1 slow: NO2CI → NO2 + CI step 2 fast: CI + NO2CI –→ NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]™[B]"... , where '1' is understood (so don't write it) for m, n etc.) Rate =

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.85PAE

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