The uranyl ion, [UO;]?", is a ubiquitous structural motif in U(VI) chemistry. The molecule is linear and the U-O bond length is approximately 2Å. When lying along the z-axis, the coordinates of uranyl can be specified by: ry = 0; TOA =0: To a) Define a 3 x 3 matrix representing a reflection in the xy-plane and show that uranyl is symmetric with respect to this symmetry operation b) Define a 3 x 3 matrix representing an arbitrary rotation of 0 radians about the z-axis and show that the uranyl molecule is symmetric with respect to this symmetry operation c) What is the point group of the uranyl molecule?

Linear Algebra: A Modern Introduction
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Chapter4: Eigenvalues And Eigenvectors
Section4.6: Applications And The Perron-frobenius Theorem
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Q3.
The uranyl ion, [UO;]²", is a ubiquitous structural motif in U(VI) chemistry. The molecule is linear and the
U-O bond length is approximately 2Å. When lying along the z-axis, the coordinates of uranyl can be
specified by:
ry = |0
TOA = 0;
TOB
a) Define a 3 x 3 matrix representing a reflection in the xy-plane and show that uranyl is
symmetric with respect to this symmetry operation
b) Define a 3 x 3 matrix representing an arbitrary rotation of 0 radians about the z-axis and show
that the uranyl molecule is symmetric with respect to this symmetry operation
c) What is the point group of the uranyl molecule?
Transcribed Image Text:Q3. The uranyl ion, [UO;]²", is a ubiquitous structural motif in U(VI) chemistry. The molecule is linear and the U-O bond length is approximately 2Å. When lying along the z-axis, the coordinates of uranyl can be specified by: ry = |0 TOA = 0; TOB a) Define a 3 x 3 matrix representing a reflection in the xy-plane and show that uranyl is symmetric with respect to this symmetry operation b) Define a 3 x 3 matrix representing an arbitrary rotation of 0 radians about the z-axis and show that the uranyl molecule is symmetric with respect to this symmetry operation c) What is the point group of the uranyl molecule?
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