The vapor pressures of each component in a mixture of propanone (acetone, A) and trichloromethane (chloroform, C) were measured at 35°C with the following results: In the above, xC is molar fraction of compound C. Check whether the mixture conforms to Raoult’s law for the component in large excess and to Henry’s law for the minor component. Provide relevant graphs with calculations. Find the Henry’s law constant for each of the two substances. If the substantial difficulties are encountered in finding the Henry’s law constants, explain what these problems are and why they occur.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter19: The Chemistry Of The Main-group Elements
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The vapor pressures of each component in a mixture of propanone (acetone, A) and trichloromethane (chloroform, C) were measured at 35°C with the following results: In the above, xC is molar fraction of compound C. Check whether the mixture conforms to Raoult’s law for the component in large excess and to Henry’s law for the minor component. Provide relevant graphs with calculations. Find the Henry’s law constant for each of the two substances. If the substantial difficulties are encountered in finding the Henry’s law constants, explain what these problems are and why they occur.
хс
Po/kPa
PA/KPa
0
0
46.3
0.20
0.40
0.60
0.80 1
4.7
11
18.9
26.7 36.4
33.3 23.3 12.3 4.9 0
Transcribed Image Text:хс Po/kPa PA/KPa 0 0 46.3 0.20 0.40 0.60 0.80 1 4.7 11 18.9 26.7 36.4 33.3 23.3 12.3 4.9 0
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