trans-1-chloro-3-methylcyclohexane as well as a chair structure

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter3: Organic Compounds: Alkanes And Their Stereochemistry
Section3.SE: Something Extra
Problem 46AP: Draw the most stable conformation of pentane, using wedges and dashes to represent bonds coming out...
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trans-1-chloro-3-methylcyclohexane as well as a chair structure.
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Conformational isomers: The conformational isomers are formed by the rotation of a carbon-carbon single bond in a compound.

In the chair conformation of cyclohexane, there are two types of hydrogen atoms, axial and equatorial hydrogen atoms. By the substitution of these hydrogen atoms, we get two types of substituents in the chair conformation of cyclohexane.

The most stable chair conformation of the given compound is that which has the bulky and most substituents present at the equatorial position. In the equatorial position, there is a large space hence less steric hindrance compared to the axial position.

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