Use a sheet of paper to answer the following question. Take a picture of your answers and attach to this assignment. Draw the major organic product formed in each of the following transition-metal catalyzed reactions: (a) (b) (c) (d) CH3 + H₂ Br RhCl(PPH3)3 Ru(=CHPh)Cl₂(PCY3)3 CH3 Br Pd(PPH3)2Cl₂ B(OH)2 When finished, make sure to click Submit Pd(OAc)₂
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- (10pts) Compound A, C10H16, was found to be optically active. On catalytic reduction over a palladium catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, CioH2o. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid (CHCOOH). The other fragment, compound C, was an optically active carboxylic acid, C8H14O2. Write reactions, and draw the correct structures for A-C, explain your answer in detail.Bromine reacts with alkenes in methanol according to the equation (see image 1). When this reaction was carried out with 4-tert-butylcyclohexene, only one isomer was formed with the molecular formula C12H23BrO (80% yield) a) Which of the following is the structure more reasonable for this compound? (see image 2) b) Explain your reasoning through a corresponding mechanism2. Draw structures corresponding to the following IUPAC names 3. Predict the products of the reaction of the following substances with Cro3 in aqueous acid
- Write the structure of the major organic product isolated from the reaction of 3-hexyne with (a) Hydrogen (2 mol), platinum (b) Hydrogen (1 mol), Lindlar palladium (c) Hydrogen chloride (1 mol) (d) Hydrogen chloride (2 mol) (e) Chlorine (1 mol) (f) Chlorine (2 mol) (g) Aqueous sulfuric acid, mercury(II) sulfate (h) Ozone followed by hydrolysis2. a. Write the complete reaction equation along with all the products that might be formed if 1-bromo-1-methylcyclohexane has an elimination reaction.b. Give the name of all the productsc. Which one is the major products? Give the explaination for your answer by writing the mechanism.On acid-catalyzed dehydration, 1-butanol (CH3CH2CH2CH2OH) can be converted to 1-butene. Write out an equation for the reaction Assign each the appropriate symbol for the mechanism of the reaction (E1 or E2) Draw a suitable mechanism for the reaction
- Write an equation for the reaction of CH2=CHCH2CH3 with each of the following reagents: a. Ozone, followed by Zn, H+ b. BH3 followed by H2O2, OH c. Bromine Can you write it out please and thank you(i) Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction. (ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.For each of the following, predict whether the reaction proceeds by an SN1or SN2 mechanism: Write the names of the product.
- 4. Compound A has the formula C 8H 8. It reacts rapidly with KMnO 4 to give CO 2 and a carboxylic acid, B (C 7H 6O 2), but reacts with only 1 molar equivalent of H 2 on catalytic hydrogenation over a palladium catalyst. On hydrogenation under conditions that reduce aromatic rings, 4, equivalents of H 2 are taken up and hydrocarbon C (C 8H 16) is produced. What are the structures of A, B, and C.A compound A, C7H12, was found to be optically active. On catalytic reduction over platinum catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, C7H16. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid. The other fragment, compound C, was an optically active carboxylic acid, C5H10O2. Write the reactions and draw structures for A, B and C.Two isomeric materials are available for your use. They are: A. 2-methyl-2-pentene (CH3)2C=CHCH2CH3B. 2-ethyl-1-butene (CH3CH2)2C=CH2 Give the name/s only (structures not required) of the product for the reaction of (i) A and (ii) B with the reagents listed below. Your answers should be given using A1 -A10 and B1-B10 as indicators.Eg. the product for your first reaction should be stated as A1 = name of product etc. HBr HOBr Ozone (O3)/Zn B2H6/H2O2 N-bromosuccinimide KMnO4/ OH- Hg (OAc)2 CH3CO2OH (Peroxyacetic acid) H2/ Pd H2/Li/NH3