Use Drago’s E and C parameters to calculate ΔH for the reactions of NH3 and BF3 and of NH3 and B(CH3)3. Compare your results with the reported experimental values of −71.1 and −64 kJ/mol for NH3—B(CH3)3 and −105 kJ/mol for NH3—BF3.  use NH3 as the base, and put the four reactions in order of the magnitudes of their ΔH values.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter20: Carboxylic Acids And Nitriles
Section20.SE: Something Extra
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Use Drago’s E and C parameters to calculate ΔH for the reactions of NH3 and BF3 and of NH3 and B(CH3)3. Compare your results with the reported experimental values of −71.1 and −64 kJ/mol for NH3—B(CH3)3 and −105 kJ/mol for NH3—BF3.

 use NH3 as the base, and put the four reactions in order of the magnitudes of their ΔH values.

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The Drago's equation helps us to calculate the enthalpy and thereby the bond strength of  acid- base or donor-acceptor interactions. It use two parameters which are empirically obtained i.e. E which describes electrostatic interaction and C for covalent interaction.

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