Use the References to access important values if needed for this question. An aqueous solution of phosphoric acid, that is 0.500 percent by weight phosphoric acid, has a density of 1.0010 g/mL. A student determines that the freezing point of this solution is -0.122 °C. Based on the observed freezing point, what is the percent ionization of the acid and the value of K? Assume that only the first ionization of the acid is important. Kf for H,0 is 1.86 °C/m. % ionized = % K1 %3D

Use the References to access important values if needed for this question. An aqueous solution of phosphoric acid, that is 0.500 percent by weight phosphoric acid, has a density of 1.0010 g/mL. A student determines that the freezing point of this solution is -0.122 °C. Based on the observed freezing point, what is the percent ionization of the acid and the value of K? Assume that only the first ionization of the acid is important. Kf for H,0 is 1.86 °C/m. % ionized = % K1 %3D

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter10: Solutions

Section: Chapter Questions

Problem 73QAP: Consider three test tubes. Tube A has pure water. Tube B has an aqueous 1.0 m solution of ethanol,...

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Consider three test tubes. Tube A has pure water. Tube B has an aqueous 1.0 m solution of ethanol, C2H5OH. Tube C has an aqueous 1.0 m solution of NaCl. Which of the following statements are true? (Assume that for these solutions 1.0m=1.0M.) (a) The vapor pressure of the solvent over tube A is greater than the solvent pressure over tube B. (b) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube A. (c) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube C. (d) The boiling point of the solution in tube B is higher than the boiling point of the solution in tube C. (e) The osmotic pressure of the solution in tube B is greater than the osmotic pressure of the solution in tube C.
Arrange the following aqueous solutions in order of decreasing freezing point. (The last three are all assumed to dissociate completely into ions in water.) (a) 0.20 m ethylene glycol (nonvolatile, nonelectrolyte) (b) 0.12 m K2SO4 (c) 0.10 m MgCl2 (d) 0.12 m KBr
A 12.0-g sample of a nonelectrolyte is dissolved in 80.0 g of water. The solution freezes at -1.94 C. Calculate the molar mass of the substance.
The freezing point of a 0.031-m solution of copper(II) sulfate in water is 0.075 C. (a) Calculate the vant Hoff factor, i, for this solution. (b) Would the vant Hoff factor be larger, smaller, or the same for a 0.050-m solution of this compound?
Sodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)
An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of 5.20C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.