Use the References to access important values if needed for this question. Solid potassium bromide is slowly added to 125 mL of a 0.0542 M silver nitrate solution. The concentration of bromide ion required to just initiate precipitation is M.
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- A mixture containing only KCl and NaBr is analyzed by the Mohr method. A 0.3172-g sample is dissolved in 50 mL of water and titrated to the Ag,CrO4 end point, requiring 36.85 mL of 0.1120 M AgNO3. A blank titration requires 0.71 mL of titrant to reach the same end point. Report the %w/w KCl and NaBr in the sample.A mixture containing only KCl and NaBr is analyzed by the Mohr Method. A 0.3172-g sample is dissolved in 50 mL water and titrated to the Ag2CrO4 endpoint, requiring 36.85 mL of 0.1120 M AgNO3. A blank titration requires 0.71 mL of titrant to reach the same endpoint. Report the % (w/w) KCl and NaBr in the sample. [Answer should be 82.41 % (w /w)]1. Titration of 0.485g sample by the Mohr method required 38.8mL of standard 0.1060 M AgNO3 solution. Calculate the percentage of chloride in the sample.
- Will Mn(OH)2 precipitate from a 0.01 M solution of MnCl2 at pH = 9? Ksp(Mn(OH)2) = 1,0 x 10-13. Discuss from solubility diagrams and prove by calculation.calculation. Co is a metal that is present in every lithium battery to stabilize its charge and toincrease stability. Every cell phone, tablet and electric car relies on the availability ofcobalt, 97% of which is extracted from mines in places like the Congo, where essentially slave labor is used.Cobalt ions form complexes with e.g. CN- . You see solubility diagrams and fraction diagrams for CoCO3 with and without the addition of 10 mM CN- .. Explain whythe solubility of cobalt carbonate increases at high pH when cyanide ions are present.Write reaction formulas for the formation of the dominant cobalt cyanide complexes.A dried sample of commercial salt was prepared by a coning and quartering. A 0.911-g sample of the salt was dissolved and diluted to 250.0 mL in a volumetric flask. Repeat 10.00-mL aliquots of this solution were titrated with a 0.054 M silver nitrate solution, requiring 9.68 mL to reach equivalence. Calculate the %(w/w) NaCl in the original sample.Which of the following statements is true regarding permanganimetry? a) Permanganate solution can oxidize water which is catalyzed by the presence of manganese dioxide or manganese ion. b) The light pink endpoint color for permanganimetry tends to fade with time due to the catalytic reaction. c) Standardization of the permanganate titrant is carried out at elevated temperature with sodium oxalate. d) all of these e) none of these
- If the molar solubility of Tl2S at 25 oC is 5.31e-08 mol/L, what is the Ksp at this temperature?Ksp = (b) It is found that 9.14e-08 g of Sc(OH)3 dissolves per 100 mL of aqueous solution at 25 oC. Calculate the solubility-product constant for Sc(OH)3.Ksp = (c) The Ksp of Cu3(PO4)2 at 25 oC is 1.40e-37. What is the molar solubility of Cu3(PO4)2?solubility = mol/LWhile working in a metal processing facility, Letlen had accidentally mixed two metal vatstogether creating an alloy. One vat was labeled for cadmium, while the other was not. It canbe assumed that these are of pure metal composition. To identify this metal, Letlen took 1.000 g of the homogenous alloy sample composed ofcadmium and the unknown metal, dissolved, and diluted it to exactly 100.0 mL in avolumetric flask. A 20.00-mL aliquot was taken and titrated this using 22.82 mL of 0.05000M EDTA. In a second 20.00-mL aliquot, the Cd was masked through the addition of HCN/NaCN buffer.The titration of the unknown metal in the aliquot required 15.13 mL of EDTA.MW: Cd (112.411 g/mol) a. Calculate the moles of Cd and the moles of unknown metal in the 20.00-mL aliquot.b. Calculate the moles of Cd and the moles of unknown metal in the sample.A piece of Gold weighing 12,359 Kg is suspected of being contaminated with Iron. To perform an instrumental analysis and To confirm whether or not it contains Fe, a portion of the sample (0.954 g) is taken from the piece and dissolved with 25 mL of aqua regia. Heats up For its complete dissolution, it is cooled and made up to 100 mL. A 10 mL aliquot is taken from this solution and made up to 50 mL. From This last solution is given the appropriate treatment to visualize Fe+2, for which the 1,10-phenanthroline reagent is added. (it forms a complex that is red in color) and is taken to a visible spectrophotometer and with a 12 mm cell a absorbance of 0.45. Previously, a calibration curve of Fe+2 was obtained under the same instrumental conditions obtaining the following data: (view table) Calculate the purity of the gold piece, assuming impurities only due to Fe.
- A 370.00 mL solution of 0.00185 M A3B4 is added to a 390.00 mL solution of 0.00100 M C3D4. What is pQsp for A3D4?How many grams of CaF2 (molar mass 78.077) will dissolve in 250 mL of 0.20 M NaF solution? The Ksp for CaF2 is 3.8904e-11.Can cadmium (II), and mercury (II) be separated quantitatively by precipitation as sulfides from a solution that is 0.15 M cadmium nitrate and 0.10 M in mercuric ions? If possible, what range of sulfide concentration is permissible? Do you expect any interference from the formation of hydroxides of both heavy metals? CdS (144.46); Ksp = 1.0 x 10 ^ -27HgS (232.66); Ksp = 2.0 x 10 ^ -53 HINT: Determine the concentration at which each of the cations start to precipitate out of solution. >Quantitative precipitation means 1/1000 remains in solution.