Use the van der Waals equation of state to calculate the pressure ? of 4.00 mol of CH4 at 469 K in a 4.20 L vessel aаGasb (L/mol)(bar · L2 /mol 2) (atm · L2 /mol 2 )2.273CH4CO2Cl22.3030.04313.6583.6100.04296.3436.2600.0542NH34.2254.1700.0371H20ХеCI402N2Kr5.4655.5374.1920.03050.05164.13719.7520.010.12811.3821.3630.03191.3701.3510.0387ArCOH2S5.1931.3551.4724.5445.1211.3361.4520.01060.03200.03950.04344.481NON201.3703.8521.3513.7990.03870.0444NO2SO25.365.290.04436.7709.4313.6484.4376.2210.05686.8659.5653.7004.5006.3090.0739HFHCl0.04060.04420.0530HBrHI

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Use the van der Waals equation of state to calculate the pressure ? of 4.00 mol of CH4 at 469 K in a 4.20 L vessel

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter5: Gases

Section: Chapter Questions

Problem 5CO: perform stoichiometric ca1cu1uions for reactions involving gases as reactants or products.

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Concept explainers

Kinetic-Theory of Gases

Kinetic theory of gases is the model or method which was developed in the 19th century by Maxwell and Boltzmann. This is possible as the interatomic force which is of short-range forces that are important for solids and liquids can be neglected for gases. This theory or gas law gives a molecular interpretation of the pressure and temperature of a gas and is consistent with gas laws and Avogadro’s hypothesis. This theory is very helpful to correctly explain the specific heat capacities of many gases, kinetic energy and it also explains the transport qualities such as viscosity, thermal conductivity, and diffusion with molecular parameters. As stated in the kinetic-molecular theory, the temperature of a substance or gas particle is related to the average kinetic energy of the particles of that substance. When a substance is heated, some of the absorbed energy is stored within the particles, while some of the energy increases the motion of the particles, called average kinetic energy.

Question

Use the van der Waals equation of state to calculate the pressure ? of 4.00 mol of CH4 at 469 K in a 4.20 L vessel

a
а
Gas
b (L/mol)
(bar · L2 /mol 2) (atm · L2 /mol 2 )
2.273
CH4
CO2
Cl2
2.303
0.0431
3.658
3.610
0.0429
6.343
6.260
0.0542
NH3
4.225
4.170
0.0371
H20
Хе
CI4
02
N2
Kr
5.465
5.537
4.192
0.0305
0.0516
4.137
19.75
20.01
0.1281
1.382
1.363
0.0319
1.370
1.351
0.0387
Ar
CO
H2S
5.193
1.355
1.472
4.544
5.121
1.336
1.452
0.0106
0.0320
0.0395
0.0434
4.481
NO
N20
1.370
3.852
1.351
3.799
0.0387
0.0444
NO2
SO2
5.36
5.29
0.0443
6.770
9.431
3.648
4.437
6.221
0.0568
6.865
9.565
3.700
4.500
6.309
0.0739
HF
HCl
0.0406
0.0442
0.0530
HBr
HI

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