Using the carbon-containing starting material(s), propose a synthesis the followingretrosynthesis scheme. Provide structures for all intermediates. The carbon atoms in theproduct must originate from the starting material(s), but you may use as many equivalents ofeach starting material as you would like, and any reagent/reaction you know. (Note: nomechanisms are required).NO2Br+он

"This isn't straightforward because you have to remember what each reagent does. By looking at the…

Answered: Using the carbon-containing starting…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations

Section11.SE: Something Extra

Problem 80AP: Amines are converted into alkenes by a two-step process called Hofmann elimination. SN2 reaction of...

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Which of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4
5) Using the carbon-containing starting material(s), propose a synthesis the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). CI s CI === ~ Br
Devise a synthesis of each of the following compounds. Besides inorganic reagents, you may use hydrocarbons and halides having ≤ 6 C′s, and CH2=CHCOOCH3 as starting materials. Each synthesis must use at least one of the carbon–carbon bond-forming reactions.
q. Outline the synthesis route for the following products, shown below. You may use any appropriate inorganic reagents, solvents. он H H From H H From OH CH,CH2 FROM H,C=CH2 CH2CHS ALCOHOLS
4. identify the structure of A and B in the following synthetic scheme: Write out complete reactions for each step, showing the structure of all reactants and products. (a) cyclohexanol +Na2Cr2O7/H2SO4, H2O -------> A (b) A + Et2NH/H2SO4 ----->B
3. Isoerythrogenic acid, C18H26O2, is an acetylenic fatty acid that turns a vivid blue on exposure to UV light. On Catalytic hydrogenation over a palladium catalyst, five molar equivalents of hydrogen are absorbed, and stearic acid, CH3(CH2)16CO2H, is produced. Ozonolysis of isoerythrogenic acid yields the following products: formaldehyde, CH2O, malonic acid, HO2CCH2CO2H, adipic acid, HO2C(CH2)4CO2H, and the aldehyde carboxylic acid, OHC(CH2)6CO2H. Provide a structure for isoerythrogenic acid.
7) Using the carbon-containing starting material(s), propose a synthesis the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). Br OH racemic = = + -Br
c) An alkyl halide E, C5H11B1 undergoes hydrolysis to form an alcohol F, C5H120. Alcohol F becomes cloudy immediately when reacted with a Lucas reagent. (i) (ii) Deduce the structures of E and F. State the type of reaction and propose the mechanism for the conversion of E to F. d) Draw the structure of the product formed when 2-bromopropane reacts with the following reagents respectively, (i) (ii) potassium cyanide ethoxide ion
Suggest readily available starting materials and reaction conditions suitable for obtaining each of the following compounds by a procedure involving alkylation of nucleophilic carbon. (a) PHCH2CH2CHPH (b) (CH3)½C=CHCH2CH2CCH2CO;CH3 ČN (c) (d) CH2=CHCH=CHCH2CH2CO,H CH3 CH2CO2H CH3 CH3CO CH;CH2CH2 (f) (e) 2,3-diphenylpropanoic acid (g) CH3Oʻ CH3CH2 CH2CH=CH2
18. Identify the products from each step in the following synthesis sequence of reactions. Show the structure of all reactants and products from each step. (a) 3-methyl-1-pentanol + PBr3 --------> A (b) A + Mg/ether-------->B (c) B + 1.CH3CH2C(O)H/2.H3O+ -------> C (d) C + Na2Cr2O7/H2SO4, H2O -----> D
The pyrolysis of acetic esters to give an alkene and acetic acid is thought to involve a planar transition state and cyclic redistribution of (4n + 2) electrons. Propose a mechanism for pyrolysis of the following ester.
Three isomeric pentanols with unbranched carbon chains exist. Which of these isomers, upon dehydration at 180C, yields only 1-pentene as a product?

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