Using the IUPAC recommendations for nomenclature, the only complex substituent that would be named in the molecule below is called C Back & (A) isopropyl (B) sec-butyl tert-butyl (D) isobutyl (E) neopentyl
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- About the underlying compound Select one: 1- slightly water soluble compound, used as drug of choice to treat copper toxicity as a 250 mg capsules in case of wilson’s disease as can form water soluble complex with it 2- the effectiveness of D-pencillamine over L-cysteine in treatment of metal toxicities despite the presence of identical ligand groups NH2, COOH and SH is due to its resistance to monoamino oxidase enzyme metabolism due to the lack of beta hydrogen 3- slightly water soluble compound, used as drug of choice to treat copper toxicity as a 250 mg capsules in case of wilson’s disease as can form water soluble complex with it 4- slightly water soluble compound, used as drug of choice to treat copper toxicity as a 250 mg capsules in case of wilson’s disease as can form water soluble complex with itRepresent a diastereoisomer of theproposed molecule, indicate theabsolute settings of your carbonschirals and discuss whether this is optically activeor not - justify:Draw all the resonance forms of the sigma complex for nitration of bromobenzene at the ortho, meta, and para positions. Point out why the intermediate for meta substitution is less stable than the other two.
- Unknown compound D,whose formula is C28H44O, is an alcohol that produces a compound whose formula is C28H50O upon catalytic hydrogenation with excess H2 over Pt.Indicate how many rings and pi bonds compound D contains based on the data given.Triphenylmethanol is insoluble in water, but when it is treated with concentrated sulfuric acid, a bright yellow solutionresults. As this yellow solution is diluted with water, its color disappears and a precipitate of triphenylmethanol reappears.Suggest a structure for the bright yellow species, and explain this unusual behavior.1Provide the necessary product(s) (i), arrows (ii)and charges (iii).
- If a compound G is reported in the literature as a pale yellow solid and when dissolved hot to purify by crystallization, the resulting solution is yellow, should the red decolorizing carbon be used before allowing the hot solution to cool? ExplainThe structures of two tertiary bicyclic chlorides (compounds 1 and 2) are shown below. Which of the following statements is correct?A) Considering compounds 2a through 2l, identify: 1)one pair of geometric isomers 2)two pairs of enantiomers and 3)three pairs of identical molecules B) Give the names, including the configurations, of each of the geometric isomers and of each of the enantiomers identified in 1A and 1B. Draw the relevant structures. C) Sort compounds 2a, 2b, 2c, 2f and 2k in order of increasing solubility in water and briefly justify.
- Using the trans effect sequence given in the text, devise rational procedures for selectively synthesizing each of the three isomers of [Pt(py)NH3NO2Cl].The sex attractant of the female housefly (Musca domestica) is called muscalure, and its structure follows. Outline a synthesis of muscalure, using the Wittig reaction. Will your synthesis lead to the required cis isomer?Naproxen is an anti-inflammatory that is the active ingredient of Aleve. Choose the compound that would be suitable for preparing the necessary diastereomeric salts to purify the racemic mixture of naproxen shown below