volumes of 1.20 M sodium hydroxide. HgHis + H* + H2His" Kal = 3.98x103 H2His + H* + HHIS²- Ka2 = 9.12x107 HHis2- + H* + His3- Ka3 = 4.67x10-10 Vol. of NAOH Calculated pH O mL 30 mL 50 mL
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- calculate the ph for each of the cases in the titration of 25.0 ml of .140 M pyrimidine with .140 M HBr (aq) The Kb of pyrimidine is 1.7 x10^-9. 1 before any addition of HBR 2 12.5 mL HBr 3 23 mL HBr 4 25 mL HBR 5 35 mL HbrThe value of Ksp for Mg3(AsO4)2 is 2.1 x 10-20. TheAsO43 - ion is derived from the weak acid H3AsO4 (pKa1 =2.22; pKa2 = 6.98; pKa3 = 11.50). (a) Calculate the molarsolubility of Mg3(AsO4)2 in water. (b) Calculate the pH of asaturated solution of Mg3(AsO4)2 in water.The measured pH of a 0.100 M solution of triethylamine (NEt3) is 11.68. What pKa of triethylammonium (HNEt3+) is implied by this data? Enter your response to the nearest 0.01.
- An experiment was performed in order to determine the concentration of a persulfate ( S2O8^-2) solution 2 I^- (aq) + S2O8^2- (aq) —> I2 (aq) + 2 SO4^2- (aq) A 25.00 mL aliquot of .1500 M KI solution was titrated to a purple blue endpoint with soduim persulfate as the titrant. The intial buret reading was 1.25 mL and the final buret reading was 15.78 mL. Calculate the concentration of the soduim persulfate. Determine the oxidation number of iodine, sulfur, and oxygen in the reaction above and determine which species is oxidized and which is reduced.Calculate the pH at 0, 50 and 100% for the titration of 100.0 mL of 0.05 M CH3NH2 with 0.05 M HCl. Kb (CH3NH2) = 4.35x 10-5 A 1.00-ml aliquot of fish oil was analyzed for N using the Kjeldahl method. After digestion, the distilled ammonia was collected in 100 ml of 0.0503M HCl. The excess HCl required 28.3 ml of 0.124 M NaOH for titration. Calculate the amount of N in the sample of fish oil as mg/mL.Sketch a titration curve for the amino acid cysteine, and indicate the pKavalues for all titratable groups. Also, indicate the pH at which cysteinehas no net charge.
- A researcher is tasked with analyzing pet food samples for total nitrogen by the Kjeldahl method. A 0.4731 g sample of pet food was analyzed, and liberated ammonia was collected in 50.00 mL of 0.184 M HCl. The excess of acid required a 12.42 mL back titration by 0.0925 M NaOH. Write results in terms of % total nitrogen and % wt protein as % histidine.1) You are asked to prepare a buffer for a protein assay. This protein works best at a slightly acidic pH of 5.5. a. From the list of Acids and conjugate bases which pair would you pick. (The list is in the attached image) b. You are asked to make a 1M stock solu on of the Buffer, how many grams of each acid and base would you need to make a 500mL stock. c. For the experiment, the final concentra on of the buffer should be 50mM. How many mL of your stock would you need to make 2L. Hint: M1V1=M2V2a student was titrating a solutin of acitic acid with a sodium hydroxid solution. determin the ph at the equivilance point. do this by constructing a bca table, constructing and ice table, writing the equlibrium constant expresion and find the ph. the ka for ch3cooh is 1.8e-5. a 50ml solutin of 0.3 m of ch3cooh was titrated with 0.3 m of naoh.
- Please sketch the titration curve of lysine. Then annotate X-axis, Y-axis, each pKa, PI and ionizable forms of lysine on the curve. Note: the value of pKa or PI is not required.Given that pKb for iodate ion (IO-3) is 13.83, find the quotient [HIO3]/[IO-3] in a solution of sodium iodate at (a) pH 7.00; (b) pH 1.00.1 How do you use the amount of 0.01 M NaOH used in titration to determine protein content? NaOH was calibrated with KHP (0.0553 g) to get an amount of 25.2 mL 0.01 M NaOH used. GR1: 71.6 mL NaOH used GR2: 91.2 mL NaOH used GR3: 86.4 mL NaOH used