What is AH for the following chemical reaction? CO(g) + NH3(g)→HCN(g) + H₂O(g) You can use the following table of standard heats of formation (AH) to calculate the enthalpy of the given reaction. Element/Compound H(g) H₂(g) NH3(g) CO(g) C(g) C(s) Standard Heat of Formation (kJ/mol) 218 0 -45.90 -110.5 71 0 Element/ Compound N(g) O₂(g) O(g) H₂O(g) HCN (g) HNO3(aq) Standard Heat of Formation (kJ/mol) 473 0 249 -241.8kJ 130.5kJ -206.6

What is AH for the following chemical reaction? CO(g) + NH3(g)→HCN(g) + H₂O(g) You can use the following table of standard heats of formation (AH) to calculate the enthalpy of the given reaction. Element/Compound H(g) H₂(g) NH3(g) CO(g) C(g) C(s) Standard Heat of Formation (kJ/mol) 218 0 -45.90 -110.5 71 0 Element/ Compound N(g) O₂(g) O(g) H₂O(g) HCN (g) HNO3(aq) Standard Heat of Formation (kJ/mol) 473 0 249 -241.8kJ 130.5kJ -206.6

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 66E: In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both...

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In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both solutions were originally at 24.6C. After the reaction, the final temperature is 31.3C. Assuming that all the solutions have a density of 1.0 g/cm3 and a specific heat capacity of 4.18 J/Cg, calculate the enthalpy change for the neutralization of HCl by NaOH. Assume that no heat is lost to the surroundings or to the calorimeter.
A sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is burned in a bomb calorimeter, sodium chloride does not burn. What is the percentage of sucrose in the sample if a temperature increase of 1.67C is observed when 3.000 g of the sample are burned in the calorimeter? Sucrose gives off 5.64103kJ/mol when burned. The heat capacity of the calorimeter and water is 22.51 kJ/C.
A 50-mL solution of a dilute AgNO3 solution is added to 100 mL of a base solution in a coffee-cup calorimeter. As Ag2O(s) precipitates, the temperature of the solution increases from 23.78 C to 25.19 C. Assuming that the mixture has the same specific heat as water and a mass of 150 g, calculate the heat q. Is the precipitation reaction exothermic or endothermic?
Magnesium sulfate is often used in first-aid hot packs, giving off heat when dissolved in water. A coffee-cup calorimeter at 25C contains 15.0 mL of water at 25C. A 2.00-g sample of MgSO4 is dissolved in the water and 1.51 kJ of heat are evolved. (You can make the following assumptions about the solution: volume=15.0 mL, density=1.00 g/mL, specific heat=4.18J/gC.) (a) Write a balanced equation for the solution process. (b) Is the process exothermic? (c) What is qH2O? (d) What is the final temperature of the solution? (e) What are the initial and final temperatures in F?
In a constant-volume calorimeter, 35.0g of H2cools from 75.3C to25.0C. Calculate w, q, U, and H for the process.
A 21.3-mL sample of 0.977 M NaOH is mixed with 29.5 mL of 0.918 M HCl in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 19.6C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, the specific heat of all solutions is the same as that of water, and volumes are additive.
Chlorine trifluoride is a toxic, intensely reactive gas. It was used in World War II to make incendiary bombs. It reacts with ammonia and forms nitrogen, chlorine, and hydrogen fluoride gases. When two moles of chlorine trifluoride react, 1196 kJ of heat are evolved. (a) Write a thermochemical equation for the reaction. (b) What is Hf for ClF3?
Sodium carbonate, Na2CO3, is used to manufacture glass. It is obtained from sodium hydrogen carbonate, NaHCO3, by heating. 2NaHCO3(s)Na2CO3(s)+H2O(g)+CO2(g) Calculate the standard enthalpy of reaction, using enthalpies of formation (Table 6.2).
Adding 5.44 g of NH4NO3(s) to 150.0 g of water in a coffee-cup calorimeter (with stirring to dissolve the salt) resulted in a decrease in temperature from 18.6 C to 16.2 C. Calculate the enthalpy change for dissolving NH4NO3(s) in water, in kJ/mol. Assume the solution (whose mass is 155.4 g) has a specific heat capacity of 4.2 J/g K. (Cold packs take advantage of the fact that dissolving ammonium nitrate in water is an endothermic process.)
Another reaction that is used to propel rockets is N2O4(l)+2N2H4(l)3N2(g)+4H2O(g) This reaction has the advantage that neither product is toxic, so no dangerous pollution is released. When the reaction consumes 10.0 g liquid N2O4, it releases 124 kJ of heat. (a) Is the sign of the enthalpy change positive or negative? (b) What is the value of H for the chemical equation if it is understood to be written in molar quantities?
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When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?