What is the overall order of the reaction? b. Write the rate expression. c. Calculate the rate constant, k. d. If the concentration of MnO4-, H2C2O4, & H+ are 0.155 M, 0.293M, and 0.475M respectively, what is the rate of the reaction?

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Chapter18: Electrochemistry
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Problem 4RQ: Consider the equation G = -nF. What are the four terms in this equation? Why does a minus sign...
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a. What is the overall order of the reaction?

b. Write the rate expression.

c. Calculate the rate constant, k.

d. If the concentration of MnO4-, H2C2O4, & H+ are 0.155 M, 0.293M, and 0.475M respectively, what is the rate of the reaction?

For the following reaction 4 experiments have been run and the data collected is in the
following table:
2 MnO, (aq) + 5 H,C,0, (aq)
+ 6 H* (aq)
2 Mn2+ (aq) + 10 CO2 (g) + 8 H,0 (1)
Experimen
[MnO,], M
[H,C,O,], M
[H*], M
Rate, M/s
t
1
0.2410
0.3470
0.2690
0.1147
2
0.3260
0.6210
0.2270
0.2776
3
0.5630
0.5740
0.7420
0.4431
4
0.2410
0.3470
0.3840
0.1147
0.4140
0.5740
0.5610
0.3258
6.
0.3260
0.4930
0.4910
0.2203
Transcribed Image Text:For the following reaction 4 experiments have been run and the data collected is in the following table: 2 MnO, (aq) + 5 H,C,0, (aq) + 6 H* (aq) 2 Mn2+ (aq) + 10 CO2 (g) + 8 H,0 (1) Experimen [MnO,], M [H,C,O,], M [H*], M Rate, M/s t 1 0.2410 0.3470 0.2690 0.1147 2 0.3260 0.6210 0.2270 0.2776 3 0.5630 0.5740 0.7420 0.4431 4 0.2410 0.3470 0.3840 0.1147 0.4140 0.5740 0.5610 0.3258 6. 0.3260 0.4930 0.4910 0.2203
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