When heated, the DNA double helix separates into two random-coil single strands. When cooled, the random coils re-form the double helix: double helix ⇌2 random coils.(a) What is the sign of ΔS for the forward process? Why?(b) Energy must be added to overcome ΔH bonds and dispersion forces between the strands. What is the sign of ΔG for the for-ward process when TΔS is smaller than ΔH?(c) Write an expression that shows T in terms of ΔH and ΔS when the reaction is at equilibrium. (This temperature is calledthe melting temperatureof the nucleic acid.)
When heated, the DNA double helix separates into two random-coil single strands. When cooled, the random coils re-form the double helix: double helix ⇌2 random coils.(a) What is the sign of ΔS for the forward process? Why?(b) Energy must be added to overcome ΔH bonds and dispersion forces between the strands. What is the sign of ΔG for the for-ward process when TΔS is smaller than ΔH?(c) Write an expression that shows T in terms of ΔH and ΔS when the reaction is at equilibrium. (This temperature is calledthe melting temperatureof the nucleic acid.)
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section12.7: Equilibrium At The Nanoscale
Problem 12.9PSP: For the ammonia synthesis reaction
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Does the entropy effect favor products? Explain your...
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When heated, the DNA double helix separates into two random-coil single strands. When cooled, the random coils re-form the double helix: double helix ⇌2 random coils.(a) What is the sign of ΔS for the forward process? Why?(b) Energy must be added to overcome ΔH bonds and dispersion forces between the strands. What is the sign of ΔG for the for-ward process when TΔS is smaller than ΔH?(c) Write an expression that shows T in terms of ΔH and ΔS when the reaction is at equilibrium. (This temperature is calledthe melting temperatureof the
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