Q: Threose is an aldose monosaccharide. The Fischer projection of D-threose is shown.
A: representation of molecules : Different types of projection formulae I)wedge&dash 2)Fischer 3)…
Q: An aldohexose would have the functional group A. See first image B. See second image C. -CH3 D.…
A: Functional group is a molecule or group of atoms that have its own characteristic property…
Q: Trehalose and maltose are both dimers of glucose. However, they have considereably different…
A: Both Trehalose and maltose are dimers that are made of two glucose. In Maltose, two glucose units…
Q: What aldoses are formed when the following aldoses are subjected to the Kiliani-Fischer synthesis:…
A: a) D-threose = The aldose synthesised by Killiani-Fischer synthesis from the given aldose is, Here,…
Q: Another hexose gives the same aldaric acid on oxidation as does d-glucose. Which one?
A:
Q: What aldoses are formed when the following aldoses are subjected to the Kiliani–Fischer synthesis:…
A: Kiliani-Fischer synthesis is a method which is used for the elongation of the carbon chains in…
Q: a. How many stereogenic centers are present in α-D-galactose? b. Label the hemiacetal carbon in…
A: Hey, since there are multiple sub-part questions posted, we will answer first three questions. If…
Q: Which of the d-aldopentoses will give optically active aldaric acids on oxidation with HNO3 ?(
A: The D-aldopentoses which which give optically active aldaric acids on oxidation with HNO3 are D-…
Q: There are three (3) vials labeled A, B, and C known to contain the following monosaccharides. All…
A: HNO3 oxidises both CHO and CH2OH group to COOH. If a molecule contain a plane of symmetry or centre…
Q: is Gulose is a c4 epimer of galactose? What should be their relationship?
A: Given, Gulose is a c4 epimer of galactose
Q: Draw the mechanism for the formation of b-lactose from α-d-galactose and β-d-glucose in dilute HCl.
A:
Q: How many stereoisomers are possible for an aldopentose?
A: We know NaBH4 is a reducing reagent it can reduce -aldehyde to alcohol. But since H- can attack from…
Q: Arrange the following sugars according to their DECREASING reactivity with Benedict’s reagent.…
A: The solution used to detect simple carbohydrates like glucose in Benedict's test is known as…
Q: Name an aldohexose other than d-glucose that is oxidized to d-glucaric acid by nitric acid.
A: The d-glucose when react with nitric acid undergo oxidation to form d-glutaric acid also known as…
Q: Given the following structure of aldose, (a) how many chiral carbons are there? (b) is it a reducing…
A: We will use this structure to answer the given questions.
Q: 1. Define the following terms briefly as they relate to the experiments. Cite an example for each…
A:
Q: Aldotetroses exist in the furanose form. Draw both anomers of D-erythrose.
A:
Q: How many aldaric acids are obtained from the 16 aldohexoses?
A: Aldaric acid is the acid having both end of the molecule equivalent due to which the position of…
Q: a) Ketotetrose. b) Ketopentose. c) Aldopentose. d) Aldotetrose. e) Aldohexose. f) None of the above
A: In this question, we will see the class of this given carbohydrate sketch. You can see details…
Q: Which D-aldopentose is oxidized to an optically active aldaric acid and undergoes the Wohl…
A: The structure of possible optically active aldaric acid from D-aldopentose are,
Q: A hexose was obtained after (+)-glyceraldehyde underwent three successive Kiliani–Fischer syntheses.…
A: The above info can be used to identify the hexose as follows:
Q: An unknown reducing disaccharide is found to be unaffected by invertase enzymes. Treatment with an…
A: From the given information it is clear that a reducing fructofuranoside is present in the given…
Q: Draw the structures of the individual mutarotating a and b anomers of maltose.
A:
Q: . Trehalose and isomaltose are both dimers of glucose. However, they have considerably different…
A: Reducing sugars are carbohydrates that act a reducing agents due to the presence of free aldehyde…
Q: Which aldoses are oxidized to optically inactive aldaric acids: (a) D-erythrose; (b) Dlyxose; (c)…
A: Given aldoses, (a) D-erythrose (b) D-lyxose (c) D-galactose
Q: Trehalose and maltose are both dimers of glucose. However, they have considereably different…
A: Consider a General Sugar If a free OH group like in above sugar is present then the sugar willl…
Q: Monosaccharide A is a diastereomer of d-lyxose. Treatment of A with nitric acid forms an optically…
A: First, the D-lyxose is shown as below by using Fischer projection. For given compound the structure…
Q: What D-aldohexose forms the same osazone as D-glucose?
A:
Q: Provide an explanation for the fact that α-D-mannose is more stable thanβ-D-mannose, whereas the…
A: Anomers are diastereomers that differ only at the hemiacetal or acetal carbon. The hemiacetal or…
Q: An unknown β-d-aldohexose has only one axial substituent. A Wohl degradation forms a compound which,…
A: Aldohexoses can form cyclic structure by fthe formation of bond between aldehydic carbon and…
Q: Predict the products obtained when d-galactose reacts with each reagent.(a) Br2 and H2O
A: The structure of D-galactose is as follows,
Q: Complete the following Fischer esterification reaction
A: Complete the following Fischer esterification reaction
Q: In solution, glucose is mostly found in the cyclic hemiacetal state, which lacks an aldehyde group.…
A: Answer - The sugar glucose may be the most commonly known hemiacetal. A hemiacetal is a carbon…
Q: Illustrate the treatment of methyl α-D-glucopyranoside with aqueous acid forms a mixture of α- and…
A: In methyl α-D-glucopyranoside, methoxy group, (-OCH3) is attached to carbon 1 and in the presence of…
Q: Draw the structure of the polyhydroxy aldehyde that cyclizes to α- and β-D-galactose
A: Galactose is a carbohydrate which is formed from carbon, hydrogen and oxygen. The general formula of…
Q: Which of the d-aldotetroses will give optically active aldaric acids on oxidation with HNO3 ?(
A:
Q: How many stereoisomers are possible for a. a ketoheptose? b. an aldoheptose? c. a ketotriose?
A: Asymmetric(chiral) centre- It is a molecule having a special arrangement of ligands which is not…
Q: Name an aldohexose other than d-glucose that is oxidized to d-glucaric acid by nitric acid. a. What…
A:
Q: How many d-aldoheptoses are possible? Draw the Fischer projection of one of them and its enantiomer.
A: When the monosaccharide unit has seven carbon atoms, it is termed as heptose. When the heptose has…
Q: How many chiral centers are in B-d-glucopyranose and a-D-galactopyranose? How many stereoisomers of…
A: Beta -D-glucopyranose and alpha-D-glucopyranose are isomers. Chiral centers is carbon having four…
Q: Which aldoses are oxidized to optically inactive aldaric acids: (a) D-erythrose; (b) D-lyxose; (c)…
A: All the aldehyde and alcohol groups on aldose are converted to the carboxylic group on oxidation…
Q: Mannose exists in aqueous solution as a mixture of a-d-mannopyranose and b-d-mannopyranose. Draw…
A:
Q: Deduce the structure of trehalose using 2,3,4,6-tetra-O-methyl-D-glucopyranose
A:
Q: Draw the anomers of d-erythrofuranose.
A: To draw the anomers of d-erythrofuranose.
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- Predict the products obtained when d-galactose reacts with each reagent. (f) excess Ac2O and pyridine (g) excess CH3 I, Ag2OPredict the products obtained when d-galactose reacts with each reagent.(a) Br2 and H2O (b) NaOH, H2O (c) CH3OH, H + (d) Ag(NH3) 2+ -OH(e) H2, Ni (f) excess Ac2O and pyridine (g) excess CH3 I, Ag2O (h) NaBH4(i) Br2, H2O, then H2O2 and Fe2(SO4)3 (j) (1) KCN/HCN; (2) H2, Pd/BaSO4; (3) H3O! (k) excess HIO42Predict the products obtained when d-galactose reacts with each reagent. (d) Ag(NH3) 2+ -OH(e) H2, Ni (f) excess Ac2O and pyridine
- An oligosaccharide isolated from an organism is found tocontain two glucose residues and one galactose residue.Exhaustive methylation followed by hydrolysis producedtwo glucoses with methoxy groups at positions 2, 3,and 6 and galactose with methoxy groups at positions2, 3, 4, and 6. What is the structure of the originaloligosaccharide?Predict the products obtained when d-galactose reacts with each reagent. (h) NaBH4(i) Br2, H2O, then H2O2 and Fe2(SO4)3