Which indicated nitrogen atom is most basic? (A) (C) (A) (D) CH3 20. What is the lowest-unoccupied molecular orbital (LUMO) of 1,3-butadiene? (C) (A) O : Br H₂C H₂O: (B) (D) 21. What is a mechanistic step for this reaction? Br₂ H₂O CH3 (B) (B) N-(C) (D) H₂O:- :Br:
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- One of the steps in fat metabolism is the hydration of crotonate to yield 3-hydroxybutyrate. This reaction occurs by addition of —OH to the Si face at C3, followed by protonation at C2, also from the Si face. Draw the product of the reaction, showing the stereochemistry of each step.Arrange the following compounds in the increasing order of reactivity towards Conc.HNO3 & Conc.H₂SO4 1. Benzene 2. Chlorobenzene 3. phenol 4. Toluene 5. Nitrobenzene A 1.2.3.4.5 (B) 5.1,243 5.1.4.2.3 D 5.2.1.4.3Arrange the following in increasing order of basic strength :C6H5NH2, C6H5NHCH3, C6H5CH2NH2
- C13b This is for my reviewer please help me with the step by step solution and answer, thank youFollowing is a structural formula for guanidine, the compound by which migratory birds excrete excess metabolic nitrogen. The hydrochloride salt of this compound is a white crystalline powder, freely soluble in water and ethanol. Q. Does proton transfer to guanidine occur preferentially to one of its -NH2 groups (cation A) or to its =NH group (cation B)? Explain.Compound A, C5H10O, is one of the basic building blocks of nature. All steroids ans many other naturally occurring compounds are built from compound A. Spectroscopic analysis of A yields the following information. a) how many double bonds and/or rings does A have? b) From the IR spectrum, what is the identity of the oxygen-conataining functional group? c) what kinds of protons are responsible for the NMR absorptions listed d) propose a structure for A
- Giventhefollowingsetofreactionsandtheirenthalpies,drawtheBorn-Habercyclefortheformationof LiCl(s)anddeterminethelatticeenergyforLiCl.Reactions:H (in kJ)(1)Li(s)Li(g);Hs= 161;(2) Li(g)Li+(g)+e–;IE= 520;(3) ½Cl2(g)Cl(g);½BE =121.5;(4)Cl(g)+ e–Cl–(g);EA= –349;(5)Li+(g)+ Cl–(g)LiCl(s);UL= ?(UL= latticeenergy)(6) Li(s)+ ½ Cl2(g)LiCl(s);Hof=–408.6._______________________________________________________________________________Is the molecular orbital diagram of 1,3-butadiene the same as cyclopenta-1,3-diene? If so how come? Doesn't the latter have 5 p orbitals or will it technically only have 4?Alcohols can undergo a lot of different reaction mechanims. If the alcohol group (OH) is attaached to an aromatic core, how will the chemistry change as compared to a typical alkyl alcohol? A) The OH group will become more polarised and more nucleophilic. B) The OH group will become more susceptible to oxidation C) The OH group will become more polarised and therefore basic D) The OH group will become more polarised and therefore acidic.
- Just do compound C1. Which of the ff. groups is an electron donating group by resonance? A. COOCH3 B. COCH3 C. N(CH3) 3+ D. NHCH3 2. Looking at the diagram. Rank the ff. hydrogen atoms in the structure below based on the order of INCREASING acidity A. H4 < H3 < H1 < H2 B. H1 < H2 < H3 < H4 C. H2 < H3 < H1 < H4 D. H2 < H1 < H3 < H4rank the set of compounds and explain briefly