Which of the following statement regarding EDTA titration is incorrect In back titration, excess EDTA is titrated with another standard solution of a second metal ion In normal direct titration, the color of the endpoint is from the metal-indicator complex In indirect titration, the analyte can not be titrated against EDTA In masking titration, the sample or the interference can be isolated by "masking"

Which of the following statement regarding EDTA titration is incorrect In back titration, excess EDTA is titrated with another standard solution of a second metal ion In normal direct titration, the color of the endpoint is from the metal-indicator complex In indirect titration, the analyte can not be titrated against EDTA In masking titration, the sample or the interference can be isolated by "masking"

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter21: Potentiometry

Section: Chapter Questions

Problem 21.25QAP

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A 100-mL sample of hard water is titrated with the EDTA solution in Problem 2. The same amount of Mg2 is added as previously, and the volume of EDTA required is 31.84 mL. a. What volume of EDTA is used in titrating the Ca2 in the hard water? _____________mL b. How many moles of EDTA are there in that volume? _____________ moles c. How many moles of Ca2 are there in the 100 mL of water? _____________ moles d. If the Ca2 comes from CaCO3, how many moles of CaCO3 are there in one liter of the water? How many grams of CaCO3 are present per liter of the water? _____________ mol / L _____________ g / L e. If 1 ppm CaCO3 = 1 mg per liter, what is the water hardness in ppm CaCO3? _____________ ppm CaCO3
Which of the following statement regarding EDTA titration is incorrect A. In indirect titration, the analyte can not be titrated against EDTA B. In normal direct titration, the color of the endpoint is from the metal-indicator complex C. In back titration, excess EDTA is titrated with another standard solution of a second metal ion D. In masking titration, the sample or the interference can be isolated by "masking"
When all of the calcium ions in the titrant is consumed, the EDTA will complex next with the indicator.(true or false) At the equivalence point, the indicator in the Mg-indicator complex is displaced by EDTA resulting in the release of the free indicator. (true or false)
What species are present in a solution giving off a pure blue endpoint in a hard water sample containing an EBT indicator (In) with an EDTA titrant? a. HIn²⁻, CaY²⁻, MgY²⁻ b. HIn²⁻, MgIn⁻, CaY²⁻, MgY²⁻, CaIn⁻ c. HIn²⁻, MgIn⁻ d. HIn²⁻, MgIn⁻, CaY²⁻
The following statements are ways to mitigate EDTA titration's low sensitivity EXCEPT A. Buffer at specific pH to avoid other metal ions to complex with EDTA B. Use of masking agents to react with other cations C. Using higher concentration of EDTA titrant D. Use of optimal form of EDTA that will complex with the target metal ion/s E. None of the choices.
Which of the following statements about the indicators used in Edta titrations is false?A. The strength of the complex made with the metal ion should be less than the complex of the same metal with EDTA.B. Metal indicators are used to determine the turning point in complexometric titrations.C. They should form water-soluble colored chelate complexes with metals.D. The complex formation constant of the complex made with metal ions must be very low.
Which of the following statements CORRECTLY describes a EDTA titration? a. All statements are correct. b. Erichrome black T has the same endpoint with Calmagite indicators and its solution is more stable than the Calmagite. c. EDTA titration can be used only for direct titration methods. d. EDTA Titration can be used in determination of all cations. e. EDTA titration is usually used in the determination of water hardness.
Precipitation Titration (Argentimetry) All of the following is true regarding Argetometric titration method except: a) The method can be used for determination of Br and I b) AgNO, is the titrant and it is not a primary standard c) In Fajan's method excess amount of AgNO, is added then back titrated with Thiocyanate d) Different methods can be used for detecting the end point e) Fajan's method depends on using fluorescence indicators such as Dichlorofluorescine
In the redox-dichromate titration with solutions containing 2 components, the first inflection point in the titration curve is due to the a) stronger oxidizing agent. b) stronger reducing agent. c) more concentrated analyte. d) less concentrated analyte. e) none of these
What is the acid/base ratio? Why is it important in the titrimetric process? (Particularly in Double Indicator Titration Method in Determination of % SO3in a Soluble Sample)
Advantages of potentiometric titrations over 'classical' visual indicator methods: (select the correct statement(s)). Can be used for colored, turbid or fluorescent analyte solution. Can be used if there is no suitable indicator or if the color change is difficult to visualize. Both answers 1 and 2 are correct
Which of the following statements is true regarding permanganimetry? a) Permanganate solution can oxidize water which is catalyzed by the presence of manganese dioxide or manganese ion. b) The light pink endpoint color for permanganimetry tends to fade with time due to the catalytic reaction. c) Standardization of the permanganate titrant is carried out at elevated temperature with sodium oxalate. d) all of these e) none of these