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- Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) KMnO4, H3O+ CH3Cl, AlCl3 HNO3, H2SO4 Cl2, FeCl3 fuming sulfuric acidWhich of the reagents listed below would efficiently accomplish the transformation of CH 3CH 2CH=CHCH 2CH 2CHO into CH 3CH 2CH 2CH 2CH 2CH 2CH 2OH? A. KMnO4 B. NaBH4 C. Br2 in CCl4 D. H2, Ni E. Two of the aboveChoose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) Br2, FeBr3 Na/NH3, -33 degrees C NBS, light KMnO4, H3O+ Mg metal, ether KOH, EtOH, heat
- (a) Which of the alcohols listed below would you expect to react most rapidly with PBr3? (CH3CH2)2CH(OH)CH2CH3 CH3CH2CH2CH2CH2CH2OH (CH3CH2)3COH (CH3CH2)2CHOHCH3 1. (b) The conversion of 3-methyl-1-octanol to 1-bromo-3-methyloctane is best achieved through use of which of these reagents in a low temperature reaction? Conc. HBr NaBr, H2SO4 Br2 PBr3Indicate the reagents for the transformation: hex-3-en-2-one → 3,4-dibromohexan-2-oneGive the reagents and reaction conditions for the conversion of (i), (ii), (iii), (iv) and (v) CH3CH2Br ➡ A ➡ CH3COOH (i) (ii) A ➡ CH3CHO ➡ B ➡ CH3CH(OH)COOH (iii) (iv) (v) What type of reaction is step (i), (ii), (iii), & (iv).
- What are the reaction products of (R)-3-methylcyclohexene in the reaction sequence of hydroboration-oxidation: I- (1S,2R)-2-methylcyclohexanol + (1R,2R)-2-methylcyclohexanol, barely II- (1S,2R)-2-methylcyclohexanol + (1R,2S)-2-methylcyclohexanol, barely III- (1S,3R)-3-methylcyclohexanol + (1R,3R)-3-methylcyclohexanol, barely IV- (1S,3R)-3-methylcyclohexanol + (1S,3S)-3-methylcyclohexanol, barely V- Alternatives I and III contain the reaction products VI- ndaWhat are the reagents used in each case below.Given the following reaction sequence: What are the reagents for reaction 8? A) H2SO4/HgSO4, H2O B) BH3 followed by NaOH, H2O2 C) any of the two
- Pick the reactant or solvent in each part that gives the faster elimination reaction.a. reaction of -OH with 1-chloro-1-methylcyclohexane or 1-chloro-3-methylcyclohexaneb. reaction of H2O with CH3CH(Cl)CH2CH3 or (CH3)2C(Cl)CH2CH3c. reaction of (CH3)3CCl with -OH in H2O or DMSOArrange the following compounds in their ease of undergoing an SN2 reaction: a. CH3CH2CH2-Cl b. (CH3)2CH-Br c. (CH3)3C-Cl d. CH3-BrA student adds NBS to a solution of 1-methylcyclohexene and irradiates the mixture with a sunlamp until all the NBS has reacted. After a careful distillation, the product mixture contains two major products of formula C7H11Br. (a)Rank these three intermediates from most stable to least stable.