Write down the rate law, indicating the order of each reactant concentration with respect to the reaction rate. (Show all your working and reasoning) 4.1 atant k including units.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter8: Properties Of Gases
Section: Chapter Questions
Problem 113QRT
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Question 4
Kinetics
The formation of manganese oxide is an important consideration for many industrial processes, including
the purification of ground water. The rate of formation, however, depends on the presence of various
inert gases, M:
Mn2+ (s) + 0z(g) + M(g) # MnO2(s) + M(g)
A petrochemical plant wants to improve their filtration procedures by using nitrogen as an inert gas (M =
N2). Their research laboratory conducted the following kinetic experiments, involving different initial
concentrations of manganese and various mixtures of nitrogen and oxygen gas:
[Mn'],
(mol dm³)
[N2].
(mol dm')
Rate
Experiment
(mol dm³)
1.25 x 102
(mol dm³ min')
2.63 X 10°
1
1.00
32.5
1.00
2.50 x 102
32.5
1.05 X 10*
3
1.00
1.25 x 102
32.5
5.25 X 10°
4.
0.500
1.25 x 102
24.4
1.31 X 10°
1.00
1.25 x 102
16.3
2.63 X 10°
Write down the rate law, indicating the order of each reactant concentration with respect to the reaction
rate. (Show all your working and reasoning)
4.1
4.2
Calculate the reaction rate constant k, including units.
Transcribed Image Text:Question 4 Kinetics The formation of manganese oxide is an important consideration for many industrial processes, including the purification of ground water. The rate of formation, however, depends on the presence of various inert gases, M: Mn2+ (s) + 0z(g) + M(g) # MnO2(s) + M(g) A petrochemical plant wants to improve their filtration procedures by using nitrogen as an inert gas (M = N2). Their research laboratory conducted the following kinetic experiments, involving different initial concentrations of manganese and various mixtures of nitrogen and oxygen gas: [Mn'], (mol dm³) [N2]. (mol dm') Rate Experiment (mol dm³) 1.25 x 102 (mol dm³ min') 2.63 X 10° 1 1.00 32.5 1.00 2.50 x 102 32.5 1.05 X 10* 3 1.00 1.25 x 102 32.5 5.25 X 10° 4. 0.500 1.25 x 102 24.4 1.31 X 10° 1.00 1.25 x 102 16.3 2.63 X 10° Write down the rate law, indicating the order of each reactant concentration with respect to the reaction rate. (Show all your working and reasoning) 4.1 4.2 Calculate the reaction rate constant k, including units.
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