CHAP. 20]
207
FIRST LAW OF THERMODYNAMICS
The Carnot cycle is the most efficient cycle possible for a heat engine. An engine that operates accordance to this cycle between a hot reservoir (Til) and a cold reservoir (Te) has efficiency
ef ' lmax =
In
Tc
I - -T
II
Kelvin temperatures must be used in this equation.
Solved Problems
20.1 III
In a certain process, 8.00 kcal of heat is furnished to the system while the system does
6.00 kJ of work. By how much does the internal energy of the system change during the process? We have
tlQ
= (8000
eal )(4.184 1leal)
Therefore, from the First Law tlQ
tlU
20.2 III
= 33 .5
k1
tlW
and
= 6.00 kJ
= tlU + tl w.
= tlQ -
tlW
…show more content…
But
Work done by motor in time
1=
(power)( l)
= (OA
hp x 746 W I hp)(l )
Equating this to our previous value for the work done yield s
I
20.7 III
=
1.26 x 10 5 J
(OA x 746 ) W
= 420 s = 7 min
In each of the following situations, find the change in internal energy of the system. (a) A system absorbs 500 cal of heat and at the same time does 400 J of work . (b) A system
CHAP. 20]
209
FIRST LAW OF THERMODYNA1"fICS
absorbs 300 cal and at the same time 420 J of work is done on it. (c) Twelve hundred calories is removed from a gas held at constant volume. Give your answers in kilojoules.
(a)
!:::"U = 2,Q - !:::"IY
(b)
= (500 cal)(4.184 llcal) -
4001 = 1.69 kl
b"U = !:::"Q -!:::"W = (300 cal)(4.184 l l cal) - (-420 1)
(e)
!:::,,[j
= b"Q -
!:::"W
= (- 1200 cal )(4.184 l/cal) - 0
=
1.68 kl
= -5.02 kJ
Notice that !:::"Q is positive when heat is added to the system. and!:::" W is positive when the system does work. In the reverse cases. b"Q and b" W mllst be taken negative.
20.8 II]
For each of the following adiabatic processes. find the change in internal energy. (a) A gas does 5 .r of work while expanding adiabatically. (b) During an adiabatic compression, 80 J of work is
4. Rowing full speed is putting maximum demands on Jim's muscles. What metabolic process is providing most of the energy for Jim’s muscles at this point and why do Jim's muscles feel like they are burning? (5 points)
Why is the parcel now warmer than it was at sea level on the windward side (what is the source of the heat energy)?
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11) When energy was studied earlier in the year, a connection was found between kinetic energy, potential energy, positive work, and negative work. What is the connection?
P4: Explain the physiology of two named body systems in relation to energy metabolism in the body
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Calculate the value of the standard free-energy change, ∆G˚, for the combustion of phenol at 25° C.
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always give out or take in energy most of the time this is heat energy
Mass of water x 4.2 (water’s specific heat capacity) x temperature change = energy transferred from the fuel to the water
3. The body changes energy, ATP, into kinetic energy making the body move or thermal energy to keep it warm.
B. There are three main stages to the thermal cycling process. Each step is repeated 20-40 times doubling
In thermodynamics, thermal energy refers to the internal energy present in a system due to its temperature. The concept is not well-defined or broadly accepted in physics or thermodynamics, because the internal energy can be changed without changing the temperature, and there is no way to distinguish which part of a system's internal energy is "thermal". Thermal energy is sometimes used loosely as a synonym for more rigorous thermodynamic quantities such as the (entire) internal energy of a system; or for heat or sensible heat which are defined as types of transfer of energy (just as work is another type of transfer of energy). Heat and work depend on the way in which an energy transfer occurred, whereas internal energy is a property of the state of a system and can thus be understood even without knowing how the energy got there.
refers to the quantity of energy needed to get work done or transfer heat e.g.
2. The relation between Heat produced (H), Work done (W.D), Mechanical Equivalent of Heat (J) is?