preview

Hydrothermal Energy Lab Report

Decent Essays

back to 1988 journal contributions by Wächtershäuser [10,15] who hypothesized that iron sulfide chemistry under hydrothermal conditions played a central role in prebiotic chemistry (i.e., the ironsulfur world). The hypothesis rests on the notion that the oxidation of FeS to form pyrite in hydrothermal submarine vent conditions provided the electrochemical power for the reduction of CO2 to organic molecules. The ``pyrite-pulled [11]'' reaction as proposed by Wächtershäuser was as follows [10,15]: FeS C H2S ! FeS2 C H2: (19) This proposed reaction provided the reducing power for the reduction of CO2 preceding the synthesis of biologically relevant compounds. Thermodynamic calculations by Schoonen et al. [438] associated with the FeS (pyrrhotite) …show more content…

A further analysis of the CO2 reduction mechanism indicated that a high activation energy exists for the transfer of electrons from pyrrhotite to CO2 (even though the overall reaction is thermodynamically favorable). Luther [439], using molecular orbital based arguments, also suggested that the HOMO of FeS (0.5 eV below the LUMO of CO2) could provide a viable reducing agent. It was also brought up that FeSaq molecular clusters are present in Fe-rich hydrothermal vent fluids, and it was recently hypothesized that such species could facilitate the reaction [1] relative to a macroscopic FeS solid. Much of the work involving transition metal sulfides and their relationships to metabolic processes has been reviewed [12,440]. It is useful in the context of this review to bring forward some selected prior studies. Keefe et al. [441] carried out studies in 1995 that investigated an aspect of the inorganic ``reverse citric acid cycle'' by reacting H2S and CO2 together in the presence of ferrous sulfide in water at 373 K. They found no production of

Get Access