Emily Schwarz
12 November 2014
The Chemistry of Natural Waters
Section: 106
Group Members: Shaily Shah, James Shank, Aaron Selnick
TA: Natalie Petrillo
Introduction: “Hard water” is a term used to refer to water which has high concentrations of magnesium, calcium, and iron ions. (Lerner, 2014) In this experiment, concentrations of magnesium and calcium ions were the main focus.
Water hardness is an important factor to consider because it has a great effect on the everyday lives of people around the world. In most places, drinking hard water does not contribute a significant amount of calcium or magnesium towards the recommended amount for the human diet, but it can in locations where the drinking water is extremely hard. The
…show more content…
Molar concentration is simply the number of moles of ions per liter of water. Parts per million is a ratio of weights, and for every one part per million, there is 1 pound of solute for every million pounds per liter. (Hardness)
EDTA titration, as well as AA (atomic absorption spectrophotometry) are two main ways in which water hardness is measured. EDTA is performed by adjusting the pH of the water with the use of a buffer, then adding an indicator to the solution, which will turn red if calcium ions are present. If only magnesium is present in the solution, it will remain blue. Then an EDTA solution is added to the solution. The complete reaction of all calcium and magnesium ions with the EDTA solution is represented by the change in color of the solution from red to blue. (Thomson, 2014)AA, or atomic absorption spectrophotometry, is performed by turning the water into an aerosol, which is then burned, and the internal computer system of the machine uses the absorbance of light to provide a number which corresponds to the concentration of ions in the water sample. (The Royal Society of Chemistry Fine Chemicals and Medicinals Group). It is important to use more than one method to measure water hardness, especially a method which relies mainly on the use of technology, to lower the possibilities for human error, as well as to provide multiple values of hardness for comparison.
In order to remove the calcium and magnesium ions from water, it is put
Four test tubes were labeled “H2O A”, “H2O B”, “Enz A”, and “Enz B”. In the test tubes labeled “Enz A” and “Enz B” 1 mL of catalase was pipetted into each, and in the test tubes labeled “H2O A” and “H2O B” 6mL of deionized water was pipetted into each. Next the two test tubes labeled A were placed into an ice bucket, and the test tubes labeled B were placed in a 50°C water bath. These were left in their respected locations for 5 minutes each, and then the temperature of the test tubes in the ice bucket were recorded. Next the “Enz A” test tube was mixed with the “H2O A” test tube and 100µL of guaiacol and 150µL of .1% H2O2 were added to this mixture using a micropipette. The test tube was then covered with aluminum foil and inverted to mix the solution and then placed in a curvette and into the spectrometer. The initial absorbance was recorded and the curvette was placed back in the ice bucket. Then the contents of the test tubes labeled B were mixed and 100µL of guaiacol and 150µL of .1% H2O2 were added to this mixture using a micropipette. This was then placed in a curvette and into the spectrometer and the initial absorbance was recorded and the curvette placed back in the water bath. Finally after 5 minutes of time had passed each of these were placed in the spectrometer again and their absorbance levels recorded. This process should be a very quick one to ensure that the
Hard water is an annoying thing that most of the American face one time or the other. According to a US geological survey, hard water is found in more than 89.3% of the country. water is a universal solvent meaning it can dissolve more substance than any other solvent, that being said water from the rain is soft water, free from any mineral but as the water basses through the air it picks up carbon dioxide and other impurities in the air, and once the water reach the ground it start to dissolve mineral and change into a hard water with mineral such as Ca+, Mg+ [1].
In the Chemistry of Natural Waters Lab we were to collect a sample of water, ranging from a fountain, stream, bottle, or tap water. After we collected the samples we all did many tests to see what the hardness was for each one. Water hardness is determined by the amount of Calcium and Magnesium in the water.(2) Water that has more Calcium or Magnesium is considered to be harder than water with less of those two elements. When you use soap and detergent, this is where you see water hardness coming into play in everyday life when you are washing things.
In the ADI Molarity Lab, the primary tasks was to use different values of moles of solute, volume of solvent, and molarity to find the mathematical relationships between them. To find these relationships, our group had to change the quantities of each of the variables and visually observe the molarity within the solution. For instance when using Cobalt (II) Nitrate to find the relationship between volume of the solution and the molarity of the solution; the group kept the amount of moles of the solute at a constant of 1.00 moles because if it would have changed it would have caused inaccurate data. We first set the volume of the solution to 0.2 liters. The molarity of the solution was 5.00 mol/L. Then we changed the volume of the solution
Molar Mass is basically in grams per mole for example salt has a molar mass of 5.8g per mole. The mass of an element refers to 6.0221415x1023 molecules of the substance. Molar Mass helps us figure out how many grams per mole we need to do this project and it helps us know how much we need to put into the solution. If you don’t Find
The Results from ETDA (table 7) show that tap water Mifflin Hall (400 ppm) is hardest than the four other water samples. It is followed by tap water Harleysville (340 ppm), well Water Wyckoff (320 ppm), Stream Water Raleigh (110 ppm) and Tap water Yosemite (80 ppm). This order supports my hypothesis. Tap water Yosemite is relatively soft compared to the other water samples. I have predicted my sample to be the hardness and tap water Yosemite to be the softest. Also, these results support my hypothesis in the assumption that they show that stream water Raleigh is moderately hard as expected. Nevertheless, I expected tap water Yosemite to be relatively soft but the data show that it is moderately hard. In fact, I assumed that tap water Yosemite would be slightly hard because in California ground water is stored in alluvium. They are made up of loose gravel, sands, and silts and they contain a very low concentration of divalent cations. Maybe the fact that rocks vary from the state of California due to the difference in geology might
“Hard water is water that contains cations with a charge of +2, especially Calcium and Magnesium.” This is a direct quote from Professor Rachel Casiday and Regina Frey from the Department of Chemistry at Washington University. Essentially, water hardness is the minerals that are built up into the ground water that can have several different effect on the water. It is determined by several different cations, but in this experiment, only by the amount of Ca^(2+) and Mg^(2+). Water is an absolute necessity to life. “About 80 liters of water per person per day is required to sustain a reasonable quality of life” (PSU Chemtrek). Being able to determine the quality of the water you drink is needed in order to maintain good health.
Not all water is alike. In fact, water contains minerals that change its properties. According to the University of Washington in St. hard water is hard water is “water that contains cations with a charge of +2, especially Ca2+ and Mg2+”1. Water picks up these Ca2+ and Mg2+ cations as it moves through soil and interacts with sedimentary rock undergoing a process known as dissolution. Water hardness values can be represented in numerous ways, including milligrams per liter, parts per million, and grains per gallon. The water hardness value becomes greater with the increase in concentration of these cations2. The water hardness in State College, PA is rather high due to the location of the town being on a large amount of limestone3.
The minerals contained in hard water have a wide impact on your life and home. Hard water affects almost any task requiring water. Fortunately, you can reduce water hardness by contacting our plumbers in Sugar Land and scheduling the installation of a water softener on your water supply line. Once installed, the softener will protect your pipes, appliances, and generally make your life easier.
Water is essential for agricultural production, and natural tap water is the best choice for the watering needs associated with agriculture. Whether it is through irrigation to provide crop water requirements, or is largely supplementary to existing watering measures, using tap water over using bottled water is the only sensible way to accomplish meeting the demands necessary for the watering needs of agriculture. Imagine all of the time, energy, effort, and labor involved with the inconvenient method of watering crops, livestock, and other areas of agriculture with bottled water. Using the bottled water for this purpose would be impractical, especially when the much simpler and obvious method of using tap water exists. When looking at cost comparisons involving agriculture, it is economically cheaper to use tap water than it is to use bottled water. Of course, this savings in water usage is to the advantage of the farmer. For all of these reasons, I believe using natural tap water is the best option for water usage in agriculture.
Water hardness is the presence of dissolved divalent calcium and magnesium cations in a liquid solution such as water. Hard water has more cations, soft water has less cations. Calcium and magnesium is present in many different water supplies because these minerals are in rocks and soils. The Calcium comes from sedimentary rocks such as limestone and dolomite, while Magnesium comes from rocks like olivine and pyroxenes -------earth materials book. Hardness has an affect on the way our water tastes, hydro book. . it will leave a scaly deposit on the inside of pipes, boilers, and tank - the water evaporates leaving behind rocklike deposits consisting mostly of calcite crystals Hard water can be softened at a fairly reasonable cost, but it is not always desirable to remove all the minerals that make water hard. Extremely soft water is likely to corrode metals, although it is preferred for laundering, dishwashing, and bathing. help reduce the chemical bonds between dirt and the surface make it easier to be cleaned. The titration is a very inexpensive experiment that takes a few minutes to perform. The use of AA is a very large, expensive machine which takes merely seconds. Understanding basic water softening techniques is important because we treat water in real life that way. Hard water is passed through a cylinder containing resin beads that have been saturated with sodium. The resin beads have a negative charge and are attached to positively charged sodium
The total population heart disease mortality rate versus water hardness was first analyzed and a positive correlation of 0.427 was obtained. The R2 value was found to be 0.183 indicating that 18.3% of
I would like to phrase the question in another way, which is how would I determine the representative sample and then accordingly what the constituents to be sampled?. As representative sample would be the least number of data points required to give way a statistically precise picture of the water body being analyzed. The chemistry and physic of either river or lake is a function of the substances that contact with either in-flowing or still water and how long been there with their exposure to the sunlight or wind. The constituents from varied sources that are entering or leaving (river/lake) can be a function of the hydrology and topography system. Water from sources such as direct/indirect precipitation, surface runoff from snowmelt, or storm water from exposed rock or packed soil, or groundwater inflow from the aquifer will react with the soil or bed/sedimentary rock and dissolved them (as the phenomena knowns weathering condition).Therefore these variable sources can add a critical deposit into the river or lake (surface water) constituents. For instance, many lakes and rivers sensitive to acidification due to the acid precipitation/ mine drainage, or to the atmospheric inputs such as (dust, SO4, NO3, Cl) leaving no time for neutralization before reaching lakes and rivers. Further, seasonally variation for the snowmelt, dry period, runoff, discharge can be explained by a plot of chemistry versus time or discharge depending upon the site. Major cations such as H+ from pH
Hardness is the property of water on account of which it consumes soap without form-ing lather freely. Multivalent metallic cations, (Calcium, Magnesium, Iron, Manganese, Strontium, Aluminium) in solution contribute to hardness in
Elevated amounts of salts may influence the essence of drinking water. Chloride specifically has a low taste limit. Sodium and magnesium sulfate levels in drinking water may deliver a diuretic impact and diminish the suitability of a water supply to graze creature