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The direct deposition of Ti64 onto a 410 grade stainless steel base plate resulted in a very fine

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The direct deposition of Ti64 onto a 410 grade stainless steel base plate resulted in a very fine microstructure which transitions into a coarser one towards the Ti64 layer, as seen in Figure 1. FeTi intermetallics are commonly form during traditional fusion welding, as well as diffusion bonding of Ti based and Fe based alloy [1-5]. Microstructure along the interface seen in the current study was similar to that obtained by diffusion bonding of micro duplex steel to Ti64 alloy by Orhan et al. [30]. A crack is visible in the figure, which is representative of the entire bonded region. We hypothesize that cracking occurred due to residual stresses brought about by the differences in thermal properties between the two materials. Similar …show more content…

Bright and dark regions along the NiCr and Ti64 interface observed in the current study were similar to the interface morphology observed by Kundu et al. Similar unmelted particles in CoCrMo-Ti64 compositionally graded structures were also reported by Balla et al. [16] that was also processed via LENSTM. However, in the current work, these regions are completely spherical as opposed to the earlier studies where the regions were elongated or needle like. Such difference is hypothesized due to availability of time for diffusion. Diffusion bonding is carried out for a longer time and hence there is more diffusion across the interphase where as the LENSTM based solidification is a rapid process. The bright regions along the interphase observed are intermetallics of Ti64 and NiCr alloys. Based on the EDS mapping and published literature data [18, 20, 21], possible intermetallic phases are Ni3Ti, NiTi, Ti2Ni and β-Ti. Further investigation is needed to confirm different phase formation in these layers.
EDS analysis of this sample in Figure 5 reveals that these structures contains more diffused Ni into Ti64 region than Ti in the NiCr region. From the bonding perspective this is good since it prevents Ti from diffusing towards the Fe rich region and subsequently prevents the formation of Fe-Ti based intermetallic phase formation that are inherently brittle and mostly responsible for reducing the bond strength of the joint [2, 3, 5].

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