. ionization of Cl2 (Cl2 —> Cl2+ + e-) leads to a shortening of the Cl-Cl distance (199 pm in Cl2, 189 pm in Cl2+), why?

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter6: Covalent Bonding
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1. ionization of Cl2 (Cl2 —> Cl2+ + e-) leads to a shortening of the Cl-Cl distance (199 pm in Cl2, 189 pm in Cl2+), why?

2. why the C-O bond distance is nearly identical in CO (113 pm) and CO+ (112 pm)?

3. Derive the MO diagram of a linear C-H (i.e. one carbon atom bonded to one hydrogen atom). Draw out the MOs for orbitals containing electrons  Would you expect C-H to behave as a carbocation, carbanion, or radical? Would removal of one electron from C-H to generate C-H+ increase or decrease the bond length between carbon and hydrogen? 

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