.00 mL of a nitric acid solution of unknown concentration is pipetted into a 125-mL Erlenmeyer ask and 2 drops of phenolphthalein are added. A 0.150M sodium hydroxide solution (the titrant) is bocd to titrate the nitric acid solution (the analyte), If 12.75 mL of the titrant is dispensed from a et in causing a color change of the phenolphthalein, what is the molar concentration of the nitric Sin acid solution

.00 mL of a nitric acid solution of unknown concentration is pipetted into a 125-mL Erlenmeyer ask and 2 drops of phenolphthalein are added. A 0.150M sodium hydroxide solution (the titrant) is bocd to titrate the nitric acid solution (the analyte), If 12.75 mL of the titrant is dispensed from a et in causing a color change of the phenolphthalein, what is the molar concentration of the nitric Sin acid solution

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.28QAP

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A monoprotic organic acid that has a molar mass of 176.1 g/mol is synthesized. Unfortunately, the acid produced is not completely pure. In addition, it is not soluble in water. A chemist weighs a 1.8451-g sample of the impure acid and adds it to 100.0 mL of 0.1050 M NaOH. The acid is soluble in the NaOH solution and reacts to consume most of the NaOH. The amount of excess NaOH is determined by titration: It takes 3.28 mL of 0.0970 M HCl to neutralize the excess NaOH. What is the purity of the original acid, in percent?
A bottle of concentrated hydroiodic acid is 57% HI by weight and has a density of 1.70 g/mL. A solution of this strong and corrosive acid is made by adding exactly 10.0 mL to some water and diluting to 250.0 mL. If the information on the label is correct, what volume of 0.988 M NaOH is needed to neutralize the HI solution? Suggest an indicator for the titration.
Consider the following two acids: In two separate experiments the pH was measured during the titration of 5.00 mmol of each acid with 0.200 M NaOH. Each experiment showed only one stoichiometric point when the data were plotted. In one experiment the stoichiometric point was at 25.00 mL added NaOH, and in the other experiment the stoichiometric point was at 50.00 mL NaOH. Explain these results. (See Exercise 113.)
If 55 mg of lead(II) sulfate is placed in 250 mL of pure water, does all of it dissolve? If not, how much dissolves?
Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory as a primary standard. It has the formula KHC8H4O4. This is often written in the short-hand notation as KHP. If 25.0mL of a potassium hydroxide solution are needed to neutralize 2.26g of KHP, what is the molarity of the potassium hydroxide solution? Potassium hydrogen phthalate sometimes called potassium biphthalate, as shown on this bottle is an acid that is convenient to store and use because it is a solid.
Nickel(II) formate [Ni(HCO2)2] is widely used as a catalyst precursor and to make metallic nickel. It can be prepared in the general chemistry laboratory by treating nickel(II) acetate with formic acid (HCO2H). Ni(CH3CO2)2(aq) + 2 HCO2H(aq) Ni(HCO2)2(aq) + 2 CH3CO2H(aq) Green crystalline Ni(HCO2)2 is precipitated after adding ethanol to the solution. (a) What is the theoretical yield of nickel(II) formate from 0.500 g of nickel(II) acetate and excess formic acid? (b) Is nickel(II) formate paramagnetic or diamagnetic? If it is paramagnetic, how many unpaired electrons would you expect? (c) If nickel(II) formate is heated to 300 C in the absence of air for 30 minutes, the salt decomposes to form pure nickel powder. What mass of nickel powder should be produced by heating 253 mg of nickel(II) formate? Are nickel atoms paramagnetic?
Describe how the amount of sodium hydroxide in a mixture can be determined by titration with hydrochloric acid of known molarity.
An acid is titrated with NaOH. The following beakers are illustrations of the contents of the beaker at various times during the titration. These are presented out of order. Note: Counter-ions and water molecules have been omitted from the illustrations for clarity. (a) (b) (c) (d) (e) a. Is the acid a weak or strong acid? How can you tell? b. Arrange the beakers in order of what the contents would look like as the titration progresses. c. For which beaker would pH = pKa? Explain your answer. d. Which beaker represents the equivalence point of the titration? Explain your answer. e. For which beaker would the Ka value for the acid not be necessary to determine the pH? Explain your answer.
Follow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.
Explain how to choose the appropriate acid-base indicator for the titration of a weak base with a strong acid.