QUESTION 6Give detailed mechanisms of the following reactions. Where possible, classify each step according toBaldwin's rulesPage 5 of 6(1)NO TONBuySnhBenzene, 80 °C73%NC(iii)24dBu:SinhToluene, refluxBu SnH (1.1 eq), AIBN (cat)Benzene, 80 °C, 80%NCHCN

Answered: Image /qna-images/answer/1255b3fb-f6b8-4717-a153-de69d91b8cef.jpg

Answered: (0) (ii) € NC CN D BusSnH Benzene, 80…

(0) (ii) € NC CN D BusSnH Benzene, 80 °C 73% Bu Sinh Toluene, reflux Bu SnH (1.1 eq), AIBN (cat) Benzene, 80 °C, 80% NC H CN pax ERO Page 5 of 6

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 38MP: Benzenediazonium carboxylate decomposes when heated to yield N2, CO2, and a reactive substance that...

See similar textbooks

Related questions

Q: c- Fill in the table with all 'H NMR characteristics for each signal and write down pertinent…

Q: Describe if the following reaction is spontaneous or non-spontaneous based on enthalpy, entropy and…

Q: Consider 1n NO and NO2 and each kept in a 500mL container at 37℃.Which has a greater kinetic…

Q: In the chemical reaction used in automotive air-bag safety systems, N2(g) is produced by the…

Q: What is the advantage of using automated peptide synthesis? A) No side products are formed. B) Ease…

A: Automated peptide synthesis is a fast and easy to synthesize many peptides simultaneuosly. It…

Q: A a. Draw the structure of both products B and C of these following transformations. ( 1) O3,…

Q: The reagent for the preparation of alanine from acetaldehyde is? A) NaCN, NH4Cl B) HCN C) NH3 D)…

Q: NaOH 1-(2-hydroxy cyclochexyl) ethanone

Q: Q11. Write a balanced chemical equation for this reaction complete ionic equation and the net ionic…

Q: what is the use and application of methyl salicylate

Q: At what temperature in K, will the average velocity of O2 gas be 515 m/s? Express your answer in…

A: Given that the average velocity of O2 gas = 515 m/sec The temperature at which average velocity of…

Q: 4000 100 38898 IR Spectrum (liquid film) 80 MMMMM % of base peak 10 3000 43 40 13C NMR Spectrum (50…

Q: Give the IUPAC names (including E,Z and R,S designations) for the following compounds: (a) (b) Jay…

Q: O 4000 100 80 60 IR Spectrum (liquid film) 40 20 v (cm') 87 M = 146 (<1%) 40 80 120 160 m/e 13C NMR…

Q: Consider the structure of the TAG below and answer the questions that follow. Select your answer…

A: #1: The given molecule is a triacylglycerol (TAG) that is made by the dehydration reaction between…

Q: Determine the entropy of * CO₂(g) CaCO3(s) → Cao(s) + CO₂ positive

A: Entropy can be defined as degree of randomness in a system.

Q: What is the change in internal energy in joules when a system releases 154 J of heat and does 125 J…

Q: General formula of aromatic - 22/ .compounds are A - CnH2n. B - CnHn+2. O C - CnH2n-2. O

A: Aromatic compounds are composed of a planar ring and pi-electron cloud is delocalized above and…

Q: What is the Gibbs free energy for the reaction below at standard conditions? 3Pb(s) + 2Cr3+ (aq) =…

Q: In the presence of the ester group, amide group, and hydroxyl group, the parent name of the compound…

Q: .The unit of specific gravity is - 51 A - g/cm2. O B - Without unite. O C-g/cm3. O

A: Specific gravity is the ratio between the density of substance to the density of reference…

Q: QUESTION 11 What is the radioactive particle released in the following nuclear equation? 385,90 →…

A: Given reaction: Sr9038 → Y9039 + ? We have to find the radioactive particle that is released in this…

Q: The following information is given for silicon at 1 atm: T2355.00°C Tm 1410.00°C AHvap (2355.00°C) =…

Q: INTERACTIVE CAAMIT Calc Consider the reaction of sulfuric acid, H₂SO4, with sodium hydroxide, NaOH.…

Q: .Acetylene molecule C2H2 is - - 47 A -Polar O B - Not polar Cycloalkanes are alkanes that - 48 .have…

Q: Which of the following reactions is an example of a redox reaction? A. CaO(s) + H2O(l) --> Ca(OH)2…

A: Redox Reaction :- As the name suggest that redox reaction are those in which reduction and oxidation…

Q: The Gibbs free energy is given below. Use it to determine the equilibrium constant of the reaction…

Q: نقطة واحدة نقطة واحدة نقطة واحدة which involve. .9 ********** large number of small molecules called…

Q: Rank the following aromatic hydrocarbons below in terms of increasing rates of sulfonation via…

A: Electrophilic aromatic substitution reactions : Electrophilic aromatic substitution reactions are…

Q: Write the condensed electron configuration (SPDF notations) for the following atoms and ions: Br…

Q: 29- The hybridization of carbon atom in alkene is. OA-30+1 πt. n. OB-40 OC-20+21 4 30 - The…

A: 29. Hybridization of carbon in Alkene is 3 Sigma + 1 pie bond , SP2 hybridized.

Q: 10 .occurring polymer is A. Polyethene. O B. PVC. O C. Wool. O which naturally..

A: A polymer is composed of very large molecules called macromolecules. These are made from simpler…

Q: Select the arrow drawing that best describes this step of an E1 reaction. H I-0: І H3C I нн i 1-0:…

Q: Determine the oxidation number of Phosphorus in the following. Show full calculations. Na3PO4 b.…

A: Given, a) Na3PO4 b) PO3 3- Thr oxidation number for P(Phosphorus) in both compounds/ion is:

Q: Calculate the pH of a 0.1M solution of protonated methylamine (pKa =7)

Q: 87 g of NaOH in 306 g of NaOH solution express 2 sig

A: Given, Mass of solute = 87 g Mass of solution = 306 g % m/m = =mass of solute ×100/mass of solution…

Q: a) Sonand b) an LOH H₂C e) OP HN

Q: 7) A galvanic cell is being made of iron & chromium. The standard reduction potentials are: Fe^2+…

A: Here we are required to find the standard cell potential of the given electrochemical reaction

Q: Consider the chemical reaction below. Propose a mechanism. CI af ly N N EtOH A

A: Alkyl halide gives an elimination reaction by reacting with ethanol and heating. E1 reaction…

Q: 21 - The general formal for alkanes compounds is. A - CnH2n. B - CnHn+2. C - CnH2n+2. B 22- General…

Q: Which of the following compounds have E-configuration? A) Ph COOH Ph COOH B) C) CH3 CH3CH₂ FC CH₂Br…

A: Cis configuration is called Z-configuration. If higher priority group are on same side of double…

Q: a) b) c) HO OH Hg(OAc)2 H₂SO4, H₂O PCC CH₂Cl₂ no necessary reagents for this equilibrium

Q: For the cell shown, the measured cell potential, Ecell, is -0.3657 V at 25 °C. Pt(s) | H₂(g, 0.777…

A: Given-> 2H+(aq) + 2e- ------> H2(g) E°= 0.00 V Cd2+(aq) + 2e- -------> Cd(s) E°= -0.403 V…

Q: Consider this reaction: 2HI (g) → H₂(g) + 1₂ (8) At a certain temperature it obeys this rate law. =…

Q: Consider the following reaction: Zn(s) + CuSO4(aq)  ZnSO4(aq) + Cu(s) Which of the following…

Q: 2 NaN3(s) → 2 Na(s) + 3 N₂(g) What mass of NaN3 is required to provide 40.0 L of N₂ at 25 °C and 780…

Q: The cyclization of which of the following compounds, CHO CHO CHO НО- -Н HO-H НО- -Н НО- -Н H-OH Н-…

A: Cyclization of glucose is the group characteristic of hemiacetal. When ketose cyclizes, hydroxyl…

Q: Draw the structures of the products B and C of the following reactions and 2.Draw the detailed…

Q: = (b) Calculate the pH of 0.0005 mol dm³ ethanoic acid when its pK₁ = 4.75 CH₂COOH(aq) à CH₂COO (aq)…

Q: IR Spectrum (quad fam) 4000 100 80 60 40 S 20 % of base peak 3000 2000 45 40 13C NMR Spectrum (50.0…

Question

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Step by step

Solved in 6 steps with 6 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Selection Rules for Pericyclic Reactions

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a refrigerator, and left for aparty. When he returned from the party, he discovered that the refrigerator was broken and that it had gotten quite warminside. Although all the THF had evaporated from the flask, he treated the residue with basic hydrogen peroxide. Tohis surprise, he recovered a fair yield of decan-1-ol. Use a mechanism to show how this reaction might have occurred.(Hint: The addition of BH3 is reversible.)
As measured by their first-order rate constants, the compound shown (R = CH3) undergoes hydrolysis 26 times faster than 2-chloro-2-phenylpropane (R = H) in 90% acetone–10% water at 25°C. Offer a resonance explanation for this rate difference.
Provide a reasonable arrow-pushing mechanism for Reaction 5b, and explain the the stereochemical outcome. 5d below
Propose a mechanism for the reaction in Question2.1.3.
Predict the products and mechanisms of the following reactions. Whenif more than one product or mechanism is possible, explain are the mostprobable. (f) isobutyl chloride, AgNO3 in ethanol / water (g) 1-bromo-1-methylcyclopentane, NaOEt in ethanol (h) 1-bromo-1-methylcyclopentane heated in methanol
Propose a mechanism for the reaction inQuestion 2.4
Below is a schematic representation of possible reactions that Compound X can undergo. Use the scheme to answer the following questions. What type of reaction (s) is/are represented by (i) and (ii)? Compound X undergo transitions through either [A] or [B] to produce compounds [1], [2], [3] and [4]. Draw the structures of [A] and [B]. illustrating with reaction mechanisms, show how compounds [1], [2], [3] and [4] are formed. Which of the compounds in the following pairs will occur in relatively higher yields and why?I)[1] and [2] iI)[3] and [4]
Useful Information: sodium metam: Commercial grade sodium metam is 33% pure sodium metam by weight and has a density of 1.2 g/mL. Hydrolysis of metam (Methyl isothiocynate) + H2S Rate constants for hydrolysis for metam (base catalyzed hydrolysis is negligible) = 300 mol -1 L. sec -1 , = 1 x 10-8 sec-1 Metam also undergoes photolysis to methyl isothiocyanate with a half-life of 1.6 hrs. Data for Sacramento River discharge Q = 75,000 L/min mean depth = 0.30 m pH = 7.8 mean width = 3.2 m dispersion coefficient D = 1.6 x 102 m2/min Assuming the spill acts acts as a single point source. How long does it take for the maximum contaminant concentration to get to Lake Shasta? If Na+ acts as conservative (i.e., it is not transformed) tracer, calculate the maximum concentration (in g/L) at Lake Shasta. (Hint: remember that sodium only constitutes a…
In the reaction of NaBH4 with formaldehyde in methanol sovlent, the products are BH3, CH3OH and sodium methoxide. what is the transition state for the slow step of this reaction? please give structure.
When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.
The second-order rate constant (in units of M-1s-1) for acid-catalyzed hydration at 25 °C is given for each of the following alkenes: a.Calculate the relative rates of hydration of the alkenes. (Hint: Divide each rate constant by the smallest rate constant of the series: 3.51 x 10-8.) b. Why does (Z)-2-butene react faster than (E)-2-butene? c. Why does 2-methyl-2-butene react faster than (Z)-2-butene? d. Why does 2,3-dimethyl-2-butene react faster than 2-methyl-2-butene?
I am working on a practice assignment for my organic II course and am having difficulty with a question that asks to identify the reaction sequence used to synthesize isopropylcyclopentane. I would really appreciate the help!