0.91 The photochemical decomposition of HI proceeds by e mechanism HI + hv→H+ I H + HI→H₂ + I I + I + M→I₂ + M here the rate of the first step is with = 1. (a) Show that d[HI]/dt = 29. Hence the quantum yield with respect to HI 2. (b) How many HI molecules will be decomposed when 00 kcal of 250-nm radiation is absorbed? ote: ga is the number of moles of photons absorbed per cond and per unit volume

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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20.91 The photochemical decomposition of HI proceeds by
the mechanism
HI + hv→H+I
H + HI→H₂ + I
I + I + M→ I₂ + M
where the rate of the first step is I with = 1. (a) Show that
-d[HI]/dt = 29. Hence the quantum yield with respect to HI
is 2. (b) How many HI molecules will be decomposed when
1.00 kcal of 250-nm radiation is absorbed?
Note: ga is the number of moles of photons absorbed per
second and per unit volume
Transcribed Image Text:20.91 The photochemical decomposition of HI proceeds by the mechanism HI + hv→H+I H + HI→H₂ + I I + I + M→ I₂ + M where the rate of the first step is I with = 1. (a) Show that -d[HI]/dt = 29. Hence the quantum yield with respect to HI is 2. (b) How many HI molecules will be decomposed when 1.00 kcal of 250-nm radiation is absorbed? Note: ga is the number of moles of photons absorbed per second and per unit volume
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