03-A120 g sample of cocaine, was dissolved in 7.50 mL of chloroform and placed in a sample tube having a pathlength of 5.00 cm. What was the observed rotation?"
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- If the sample of the pure R enantiomer of a molecule has a specific rotation of -40 degrees and your mixture of that molecule has an 82% ee S, what is the observed specific rotation of your sample?(-)-Cholesterol has a specific rotation of -32o. A mixture of (+)- and (-)-cholesterol was analyzed by polarimetry, and the observed rotation was 14o. What is the percent composition of the (+) isomer in this mixture?Assume 1 g of sample was dissolved in 1 mL water and the sample cell was 1 dm long.a. The specific rotation for pure R is +5.0, what percentage of the mixture is R when the observed roation is -2.0. b. The rotation for pure S=-100. What is the observed rotation of a mixture that is 20%S and 80%R? I need an easy way to solve these kinds of problem, please!!
- A solution prepared by mixing 10 mL of a 0.10 M solution of the R enantiomer of a compound and 30 mL of a 0.10 M solution of the S enantiomer was found to have an observed specific rotation of +4.8. What isthe specific rotation of each of the enantiomers? (Hint: mL * M = millimole, abbreviated as mmol)7. A 0.5 gram sample of hoodia gordonii isolated from natural sources yields an observed rotation of -0.76° when dissolved in 20 mL of chloroform and placed in a 1-dm cell. Determine the specific rotation [α] of hoodia gordonii for: (a) the entities as defined above,(b) an increase in solute from 0.5g to 1.0 g;(c) an increase in solvent from 20 mL to 40 mL; and (d) an increase in path length from 1 dm to 2 dm. Does entities defined above refer to the picture since its a hoodia gordnii? I don't even know where to start with this oneFor the following molecules: a. How many stereogenic centers are present? b. How many stereoisomers are possible for these molecules?
- When 0.018 g of cholesterol is dissolved in 1.00 mL of ether and placed in a sample cell 10.0 cm in length, the observed rotation at 20 degrees (Using the D line of sodium) is -0.0567 degrees. Calculate the specific rotation of cholesterol. specific rotation= [α] =Assign R or S configurations to each stereogenic center of isoborneol and borneol. Give the relationship between these two stereoisomers.Make sure to answer the quesi to chem below Using the priority rule, identify the configuration at each chiral center and the configuration of the double bond: For a chiral center please type EXACTLY one of the following: R or S or neither if it is not a chiral center. For a double bond please type EXACTLY one of the following: E or Z or neither if the double bond has no stereochemistry.
- name the compund, and include the chilarty centers (R or S)?Which Carbons are chiral? What is the absolute (R/S) configuration of the chiral carbon that IS NOT also part of a ring? Is it an R or S configuration? Show the priorities the using the structure below that led to this answer.The specific rotation of (R)carvone is -61o. A chemist prepared a mixture of (R)-carvone and (S)-carvone, and the mixture had an observed rotation of -47o. What is the % enantiomeric excess (ee) of the mixture?