1) 2-octane has the mass spectrum shown. Propose structures for fragment ions of m/z 99, 85, 71, 57, 43 and 29. Mass Spectrum (simplified) Cpd: n-octane C;H18 0% Relative 43 Abundance M,= 114.2355 75 57 50• 29 85 25- 114 99 10 20 30 40 50 60 70 80 90 100 110 120 130 m/e

Organic Chemistry
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ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter13: Structure Determination: Nuclear Magnetic Resonance Spectroscopy
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Problem 59GP: The mass spectrum and 13C NMR spectrum of a hydrocarbon are shown. Propose a structure for this...
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1) 2-octane has the mass spectrum shown. Propose structures for fragment ions of m/z 99, 85,
71, 57, 43 and 29.
Mass Spectrum (simplified)
Cpd: n-octane C,H,
18
% Relative
Abundance
43
Mr
= 114.2355
75-
57
50-
29
85
71
25-
114
99
10
20
30
40
50
60
70
80
90
100
110
120
130
m/e
Transcribed Image Text:1) 2-octane has the mass spectrum shown. Propose structures for fragment ions of m/z 99, 85, 71, 57, 43 and 29. Mass Spectrum (simplified) Cpd: n-octane C,H, 18 % Relative Abundance 43 Mr = 114.2355 75- 57 50- 29 85 71 25- 114 99 10 20 30 40 50 60 70 80 90 100 110 120 130 m/e
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