1) Predict the products of the following reactions. a) PHCH;CH2CH;Br + excess NH3 NaN3 b) 1-bromopentane LIAIH4 NO2 Sn, HCI LIAIH4 d) CH3NH2 + NCH, LIAIH4 Ph LIAIH4 Ph ČN Na(CH3COO);BH* g) 2-Butanone + diethylamine 1) KCN, HCN h) 2-butanone 2) LIAIH4 reducing agent

1) Predict the products of the following reactions. a) PHCH;CH2CH;Br + excess NH3 NaN3 b) 1-bromopentane LIAIH4 NO2 Sn, HCI LIAIH4 d) CH3NH2 + NCH, LIAIH4 Ph LIAIH4 Ph ČN Na(CH3COO);BH* g) 2-Butanone + diethylamine 1) KCN, HCN h) 2-butanone 2) LIAIH4 reducing agent

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.63P

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Sulfur Functional Groups

Many organic molecules contain sulfur functional groups and have their own importance in chemistry as well as biology. Some of the organic molecules which contain sulfur functional groups and the corresponding sulfur functionality is given below:

Question

Self Study/Anmines/Synthesis
Name:
1) Predict the products of the following reactions.
a) PHCH2CH2CH2BR
+excess NH3
NaN3
b) 1-bromopentane
LIAIH4
NO 2
Sn, HCI
LIAIH4
d) CH3NH2 +
CI
NCH3
LIAIH4
Ph
LIAIH4
Ph
f)
CN
Na(CH3COO);BH*
g) 2-Butanone + diethylamine
1) KCN, HCN
h) 2-butanone
2) LIAIH4
reducing agent

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