#1) Show that for a van der Waals gas, the isothermal, reversible work of expansion for 1 mole of gas is given by: w = - RT In {(V,- b) / (V; - b)} + a (1/V; – 1/V) where V, and V,are the initial and final volumes, respectively.

#1) Show that for a van der Waals gas, the isothermal, reversible work of expansion for 1 mole of gas is given by: w = - RT In {(V,- b) / (V; - b)} + a (1/V; – 1/V) where V, and V,are the initial and final volumes, respectively.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter2: The First Law Of Thermodynamics

Section: Chapter Questions

Problem 2.58E: What is the finaltemperature of0.122 mole ofmonatomic ideal gas that performs 75J of work...

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#1) Show that for a van der Waals gas, the isothermal, reversible work of expansion for
1 mole of gas is given by:
w = - RT In {(V,- b) / (V; - b)} + a (1/V; – 1/V)
where V, and V,are the initial and final volumes, respectively.

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