1. A saturated solution of Mg(OH)2 is prepared having a large excess of Mg(OH)2. Sn(NO3)2 is added to the solution. Ksp = 2.0 ✕ 10-11 for Mg(OH)2 and Ksp = 5.3 ✕ 10-26 for Sn(OH)2. a) What [Sn2+] is required to start the precipitation of Sn(OH)2? b) What [Sn2+] is required so that the [Mg2+] in solution will be 0.12 M?

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter16: Solubility And Complex Ion Equilibria
Section: Chapter Questions
Problem 63E: A solution is 1 104 M in NaF, Na2S, and Na3PO4. What would be the order of precipitation as a...
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1. A saturated solution of Mg(OH)2 is prepared having a large excess of Mg(OH)2. Sn(NO3)2 is added to the solution. Ksp = 2.0 ✕ 10-11 for Mg(OH)2 and Ksp = 5.3 ✕ 10-26 for Sn(OH)2.

a) What [Sn2+] is required to start the precipitation of Sn(OH)2?

b) What [Sn2+] is required so that the [Mg2+] in solution will be 0.12 M?

 

2. Solid NaI is added to a solution which is 0.025 M in TlNO3 and 0.015 M in AgNO3. Assume the volume remains constant. Ksp = 8.9 ✕ 10-8 for TlI and Ksp = 1.0 ✕ 10-16 for AgI.

a) Which compound precipitates first TII or AgI?
 
b) What is the concentration of the first ion precipitated when the second ion starts to precipitate?
 
 
 
3. What is the molar solubility of PbSO4 in 0.19 M MgSO4Ksp = 1.0 ✕ 10-8 for PbSO4.
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