1. A)( The product of the reaction below has been found to be a potent anticancer agent (J.Med. Chem. 2010, 6867). Predict the structure of the product of the following reaction. (Hint: reaction similar to -OH group with TSCI) CN 1 equiv. B) The following substrate is a starting material in the synthesis of compounds having opiod activity (J. Med. Chem. 2011, 957). Show all products that would result from the reaction below. (Hint : think of elimination - 3 possible products ) 1) excess CHI / NaHCO, NH 2) Ag20/ H20 Hyco 3) heat
1. A)( The product of the reaction below has been found to be a potent anticancer agent (J.Med. Chem. 2010, 6867). Predict the structure of the product of the following reaction. (Hint: reaction similar to -OH group with TSCI) CN 1 equiv. B) The following substrate is a starting material in the synthesis of compounds having opiod activity (J. Med. Chem. 2011, 957). Show all products that would result from the reaction below. (Hint : think of elimination - 3 possible products ) 1) excess CHI / NaHCO, NH 2) Ag20/ H20 Hyco 3) heat
Chapter10: Reconstitution Of Powdered Drugs
Section: Chapter Questions
Problem 5.2P
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